Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 29, Problem 61P
Interpretation Introduction
Interpretation:The amino acid that most resembles to creatine should be determined.
Concept Introduction: Amino acids are the organic molecule with two
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 29 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 29.1 - Prob. 29.1QCCh. 29.2 - Prob. 29.2QCCh. 29.3 - Prob. 29.3QCCh. 29.4 - What is the purpose of the gall bladder?Ch. 29.5 - Prob. 29.5QCCh. 29.6 - Prob. 29.6QCCh. 29 - Are nutrient requirements uniform for everyone?Ch. 29 - Is banana flavoring, isopentyl acetate, a...Ch. 29 - If sodium benzoate, a food preservative, is...Ch. 29 - Prob. 4P
Ch. 29 - Prob. 5PCh. 29 - Prob. 6PCh. 29 - Prob. 7PCh. 29 - Can a chemical that, in essence, goes through the...Ch. 29 - Prob. 9PCh. 29 - Prob. 10PCh. 29 - Prob. 11PCh. 29 - Prob. 12PCh. 29 - Prob. 13PCh. 29 - Humans cannot digest wood; termites do so with the...Ch. 29 - Prob. 15PCh. 29 - Prob. 16PCh. 29 - Prob. 17PCh. 29 - Which nutrient provides energy in its most...Ch. 29 - Prob. 19PCh. 29 - Prob. 20PCh. 29 - Prob. 21PCh. 29 - Prob. 22PCh. 29 - Is it possible to get a sufficient supply of...Ch. 29 - Prob. 24PCh. 29 - Prob. 25PCh. 29 - 30-26 Which one will be digested faster: (a) a raw...Ch. 29 - Prob. 27PCh. 29 - Prob. 28PCh. 29 - Prob. 29PCh. 29 - Prob. 30PCh. 29 - Prob. 31PCh. 29 - Prob. 32PCh. 29 - Prob. 33PCh. 29 - Prob. 34PCh. 29 - Prob. 35PCh. 29 - Prob. 36PCh. 29 - What are the nonspecific effects of vitamin E, C,...Ch. 29 - Prob. 38PCh. 29 - Prob. 39PCh. 29 - Prob. 40PCh. 29 - Prob. 41PCh. 29 - Why would many athletes believe that taking large...Ch. 29 - Prob. 43PCh. 29 - Prob. 45PCh. 29 - Prob. 46PCh. 29 - Prob. 47PCh. 29 - Prob. 48PCh. 29 - Prob. 49PCh. 29 - Prob. 50PCh. 29 - Prob. 51PCh. 29 - Prob. 52PCh. 29 - Prob. 53PCh. 29 - Prob. 54PCh. 29 - Prob. 55PCh. 29 - Prob. 56PCh. 29 - Prob. 57PCh. 29 - Prob. 58PCh. 29 - Prob. 59PCh. 29 - Prob. 60PCh. 29 - Prob. 61PCh. 29 - Prob. 62PCh. 29 - Prob. 63PCh. 29 - Prob. 64PCh. 29 - Prob. 65PCh. 29 - Prob. 66PCh. 29 - Prob. 67PCh. 29 - Prob. 68PCh. 29 - Prob. 69PCh. 29 - Prob. 70PCh. 29 - Prob. 71PCh. 29 - Prob. 72PCh. 29 - Prob. 73PCh. 29 - Prob. 74PCh. 29 - Prob. 75PCh. 29 - Prob. 76PCh. 29 - Prob. 77PCh. 29 - Prob. 78PCh. 29 - Why is it necessary to have protein in our diets?Ch. 29 - Prob. 80PCh. 29 - Prob. 81PCh. 29 - Prob. 82PCh. 29 - Prob. 83PCh. 29 - Prob. 84PCh. 29 - Egg yolk contains a lot of lecithin (a...Ch. 29 - Prob. 86PCh. 29 - Prob. 87PCh. 29 - Prob. 88P
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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