Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 29, Problem 50P
Interpretation Introduction
Interpretation: The sources of fuel (except glucose) that the brain cells can utilize are to be described.
Concept introduction: The human brain requires energy to function (such as emotions, memory, and learning) properly. Its normal functioning and overall structure can be impaired by the improper intake of food. This is because the cellular activities of the brain need energy that is taken by the breakdown of nutrients from food.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 29 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 29.1 - Prob. 29.1QCCh. 29.2 - Prob. 29.2QCCh. 29.3 - Prob. 29.3QCCh. 29.4 - What is the purpose of the gall bladder?Ch. 29.5 - Prob. 29.5QCCh. 29.6 - Prob. 29.6QCCh. 29 - Are nutrient requirements uniform for everyone?Ch. 29 - Is banana flavoring, isopentyl acetate, a...Ch. 29 - If sodium benzoate, a food preservative, is...Ch. 29 - Prob. 4P
Ch. 29 - Prob. 5PCh. 29 - Prob. 6PCh. 29 - Prob. 7PCh. 29 - Can a chemical that, in essence, goes through the...Ch. 29 - Prob. 9PCh. 29 - Prob. 10PCh. 29 - Prob. 11PCh. 29 - Prob. 12PCh. 29 - Prob. 13PCh. 29 - Humans cannot digest wood; termites do so with the...Ch. 29 - Prob. 15PCh. 29 - Prob. 16PCh. 29 - Prob. 17PCh. 29 - Which nutrient provides energy in its most...Ch. 29 - Prob. 19PCh. 29 - Prob. 20PCh. 29 - Prob. 21PCh. 29 - Prob. 22PCh. 29 - Is it possible to get a sufficient supply of...Ch. 29 - Prob. 24PCh. 29 - Prob. 25PCh. 29 - 30-26 Which one will be digested faster: (a) a raw...Ch. 29 - Prob. 27PCh. 29 - Prob. 28PCh. 29 - Prob. 29PCh. 29 - Prob. 30PCh. 29 - Prob. 31PCh. 29 - Prob. 32PCh. 29 - Prob. 33PCh. 29 - Prob. 34PCh. 29 - Prob. 35PCh. 29 - Prob. 36PCh. 29 - What are the nonspecific effects of vitamin E, C,...Ch. 29 - Prob. 38PCh. 29 - Prob. 39PCh. 29 - Prob. 40PCh. 29 - Prob. 41PCh. 29 - Why would many athletes believe that taking large...Ch. 29 - Prob. 43PCh. 29 - Prob. 45PCh. 29 - Prob. 46PCh. 29 - Prob. 47PCh. 29 - Prob. 48PCh. 29 - Prob. 49PCh. 29 - Prob. 50PCh. 29 - Prob. 51PCh. 29 - Prob. 52PCh. 29 - Prob. 53PCh. 29 - Prob. 54PCh. 29 - Prob. 55PCh. 29 - Prob. 56PCh. 29 - Prob. 57PCh. 29 - Prob. 58PCh. 29 - Prob. 59PCh. 29 - Prob. 60PCh. 29 - Prob. 61PCh. 29 - Prob. 62PCh. 29 - Prob. 63PCh. 29 - Prob. 64PCh. 29 - Prob. 65PCh. 29 - Prob. 66PCh. 29 - Prob. 67PCh. 29 - Prob. 68PCh. 29 - Prob. 69PCh. 29 - Prob. 70PCh. 29 - Prob. 71PCh. 29 - Prob. 72PCh. 29 - Prob. 73PCh. 29 - Prob. 74PCh. 29 - Prob. 75PCh. 29 - Prob. 76PCh. 29 - Prob. 77PCh. 29 - Prob. 78PCh. 29 - Why is it necessary to have protein in our diets?Ch. 29 - Prob. 80PCh. 29 - Prob. 81PCh. 29 - Prob. 82PCh. 29 - Prob. 83PCh. 29 - Prob. 84PCh. 29 - Egg yolk contains a lot of lecithin (a...Ch. 29 - Prob. 86PCh. 29 - Prob. 87PCh. 29 - Prob. 88P
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