(a) Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn. Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

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Answer 1

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Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS). Ca, ppm V, ppm SCa, arb. units SV, arb. units 20.0 10.0 14375.11 14261.02 40.0 10.0 36182.15 17997.10 60.0 10.0 39275.74 12988.01 80.0 10.0 57530.75 14268.54 100.0…

A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C. H₂O(g) + C₁₂O(g) = 2 HOCl(g) K = 0.0900 at 25°C с Calculate the equilibrium concentrations of each gas at 25 °C. [H₂O]= [C₁₂O]= [HOCI]= M Σ M

What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?

Answer 2

Question

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

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Answer 3

Question

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Expert Solution & Answer

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Answer 4

Question

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

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Answer 5

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 6

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Answer 7

Chapter 29, Problem 29.31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Answer 8

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 9

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 29 - Prob. 29.1P Ch. 29 - Problem 29.2 What form exists at the isoelectric...Ch. 29 - Problem 29.3 Explain why the of the group of an...Ch. 29 - Problem 29.5 What -halo carbonyl compound is...Ch. 29 - Problem 29.6 The enolate derived from diethyl...Ch. 29 - Problem 29.7 What amino acid is formed when is...Ch. 29 - Problem 29.8 What aldehyde is needed to synthesize...Ch. 29 - Prob. 29.8P Ch. 29 - Prob. 29.9P Ch. 29 - Prob. 29.10P

Solution Summary: The author explains that the structure of (R)- and (S) -penicillamine is to be drawn.

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Chapter 29 Solutions