Student Value Bundle: Organic Chemistry, + OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card (NEW!!)
9th Edition
ISBN: 9781305922198
Author: John E. McMurry
Publisher: CENGAGE L
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Textbook Question
Chapter 28.SE, Problem 21AP
Human brain natriuretic peptide (BNP) is a small peptide of 32 amino acids used in the treatment of congestive heart failure. How many nitrogen bases are present in the DNA that codes for BNP?
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What is the pH of a buffer made from 0.350
mol of HBrO (Ka = 2.5 × 10-9) and 0.120
mol of KBRO in 2.0 L of solution?
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aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
B
C
Br
HO
O Substitution will not occur at a significant rate.
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Complete the following reactions with the necessary reagents to complete the shown
transformation.
Example:
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2.
?
3.
018
Br
OH
Answer: H₂O, H2SO4, HgSO4
Chapter 28 Solutions
Student Value Bundle: Organic Chemistry, + OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card (NEW!!)
Ch. 28.1 - Draw the full structure of the DNA dinucleotide...Ch. 28.1 - Draw the full structure of the RNA dinucleotide...Ch. 28.2 - What sequence of bases on one strand of DNA is...Ch. 28.4 - Show how uracil can form strong hydrogen bonds to...Ch. 28.4 - What RNA base sequence is complementary to the...Ch. 28.4 - From what DNA base sequence was the following RNA...Ch. 28.5 - List codon sequences for the following amino...Ch. 28.5 - List anticodon sequences on the tRNAs carrying the...Ch. 28.5 - What amino acid sequence is coded by the following...Ch. 28.5 - What is the base sequence in the original DNA...
Ch. 28.7 - Prob. 11PCh. 28.7 - Prob. 12PCh. 28.SE - Identify the following bases, and tell whether...Ch. 28.SE - Identify the following nucleotide, and tell how it...Ch. 28.SE - Amine bases in nucleic acids can react with...Ch. 28.SE - The final step in DNA synthesis is deprotection by...Ch. 28.SE - The final step in the metabolic degradation of...Ch. 28.SE - One of the steps in the biosynthesis of a...Ch. 28.SE - One of the steps in the metabolic degradation of...Ch. 28.SE - One of the steps in the biosynthesis of uridine...Ch. 28.SE - Human brain natriuretic peptide (BNP) is a small...Ch. 28.SE - Human and horse insulin both have two polypeptide...Ch. 28.SE - The DNA of sea urchins contains about 32% A. What...Ch. 28.SE - The codon UAA stops protein synthesis. Why does...Ch. 28.SE - Which of the following base sequences would most...Ch. 28.SE - For what amino acids do the following...Ch. 28.SE - Prob. 27APCh. 28.SE - Prob. 28APCh. 28.SE - Draw the complete structure of the ribonucleotide...Ch. 28.SE - Draw the complete structure of the...Ch. 28.SE - Give an mRNA sequence that will code for the...Ch. 28.SE - Give an mRNA sequence that will code for the...Ch. 28.SE - What amino acid sequence is coded for by the...Ch. 28.SE - What amino acid sequence is coded for by the...Ch. 28.SE - Prob. 35APCh. 28.SE - Show the steps involved in a laboratory synthesis...Ch. 28.SE - Draw the structure of cyclic adenosine...Ch. 28.SE - Prob. 38AP
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- 7:34 • < Question 18 of 22 5G 50% Submit What is the pH of a buffer made from 0.220 mol of HCNO (Ka = 3.5 × 10-4) and 0.410 mol of NaCNO in 2.0 L of solution? 1 2 3 ☑ 4 5 6 C 7 8 | 9 +/- 0 ×10 Tap here for additional resources ||| Гarrow_forward6:46 ✔ 5G 58% < Question 7 of 22 Submit What is the primary species in solution at the halfway point in a titration of NH3 with HBr? A NH3 and H+ B NH₁+ and H+ C NH4+ D NH3 and NH4+ Tap here for additional resources |||arrow_forward6:49 Dji < Question 15 of 22 4G 57% Submit The pOH of a solution is 10.50. What is the OH- concentration in the solution? A 3.2 × 10-4 M B C 3.2 x 10-11 M 10.50 M D 4.2 M E 3.50 M Tap here for additional resources |||arrow_forward
- ヨ 6:49 Dji < Question 13 of 22 5G 57% Submit The pH of a solution is 2.40. What is the H+ concentration in the solution? A B 2.5 x 10-12 M 4.0 × 10-3 M C 2.40 M D 4.76 M 11.60 M Tap here for additional resources |||arrow_forwardヨ C 6:48 Di✔ < Question 12 of 22 5G 57% Submit The pH of a solution is 12.50. What is the H+ concentration in the solution? A 0.032 M B 3.2 × 10-13 M 1.5 M D 9.25 M 12.50 M Tap here for additional resources |||arrow_forwardヨ C 6:48 Di✔ < Question 11 of 22 5G 57% Submit The pH of a solution is 1.50. What is the H+ concentration in the solution? A 0.032 M B 3.2 × 10-13 M 1.5 M D 2.15 M 12.50 M Tap here for additional resources |||arrow_forward
- Use excel to plot the following titration data. Once you have done your plot, make sure to label the axes correctly. Use your graph to determine the pK, for the weak acid. Attach your plot to the back of this worksheet. A 1.0M solution of weak acid was titrated with a base and the following data was collected. Equivalents of Base pH observed 0.05 3.4 0.15 3.9 0.25 4.2 0.40 4.5 0.60 4.9 0.75 5.2 0.85 5.4 0.95 6.0arrow_forward1. Write the dissociation reaction then calculate the pH for the following STRONG substances. a. 2.5x103 M HBr b.5.6x10 M NaOHarrow_forward74. A contour map for an atomic orbital of hydrogen is shown below for the xy and xz planes. Identify the type (s, p, d, f, g . . .) of orbital. axis x axis z axis Cooo xy planearrow_forward
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