Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
Question
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Chapter 28.5, Problem 18P

(a)

Interpretation Introduction

Interpretation:

It should be identified that will a thermal 1, 3-migrations of carbon occur with whether retention or inversion of configuration.

Concept introduction:

Pericyclic reactions are “ any concerted reaction in which bonds are formed or brocken in a cyclic transition state”.  There is a single transition state from start to finish, in contrast to a stepwise reaction.

There are mainly three types of pericyclic reactions,

  1. 1) Electrocyclic reactions
  2. 2) Cycloaddition reactions
  3. 3) Sigmatropic reactions

In a sigmatropic reaction “ one new sigma-bond is formed as another breaks.”

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  1

Sigmatropic rearrangement reactions are named with digits. For example a [1, 3] sigmatropic rearrangement describe a reaction in which the residue migrates from position 1 to position 3.

Migration of carbon and hydrogen will occur in a sigmatropic rearrangement reaction.

When hydrogen migrates in a sigmatropic rearrangement, the s orbital of the hydrogen is partially bonded to both the migration origin and the migration terminus in the transition state.

Migration of hydrogen in suprafacial and antarafacial rearrangement can be represented as follows,

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  2Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  3

Migration of carbon occurs through two ways because it has a two lobed p orbital. Carbon can simultaneously interact with the migration origin and the migration terminus using one lobe of its p orbital.

Migration of carbon in suprafacial and antarafacial rearrangement can be represented as follows,

Carbon migrating with one lobe of its p orbital interacting

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  4 Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  5

Carbon migrating with both lobe of its p orbital interacting

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  6Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  7

Inversion of configuration is the inversion of a chiral center in a molecule in a chemical reaction.

Retention of configuration is the preservation of integrity of the spatial arrangement of bonds to a chiral center during a chemical reaction.

(b)

Interpretation Introduction

Interpretation:

It should be identified that will a thermal 1, 5-migrations of carbon occur with whether retention or inversion of configuration.

Concept introduction:

Pericyclic reactions are “ any concerted reaction in which bonds are formed or brocken in a cyclic transition state”.  There is a single transition state from start to finish, in contrast to a stepwise reaction.

There are mainly three types of pericyclic reactions,

  1. 1) Electrocyclic reactions
  2. 2) Cycloaddition reactions
  3. 3) Sigmatropic reactions

In a sigmatropic reaction “ one new sigma-bond is formed as another breaks.”

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  8

Sigmatropic rearrangement reactions are named with digits. For example a [1, 3] sigmatropic rearrangement describe a reaction in which the residue migrates from position 1 to position 3.

Migration of carbon and hydrogen will occur in a sigmatropic rearrangement reaction.

When hydrogen migrates in a sigmatropic rearrangement, the s orbital of the hydrogen is partially bonded to both the migration origin and the migration terminus in the transition state.

Migration of hydrogen in suprafacial and antarafacial rearrangement can be represented as follows,

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  9Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  10

Migration of carbon occurs through two ways because it has a two lobed p orbital.  Carbon can simultaneously interact with the migration origin and the migration terminus using one lobe of its p orbital.

Migration of carbon in suprafacial and antarafacial rearrangement can be represented as follows,

Carbon migrating with one lobe of its p orbital interacting

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  11 Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  12

Carbon migrating with both lobe of its p orbital interacting

Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  13Organic Chemistry, Chapter 28.5, Problem 18P , additional homework tip  14

Inversion of configuration is the inversion of a chiral center in a molecule in a chemical reaction.

Retention of configuration is the preservation of integrity of the spatial arrangement of bonds to a chiral center during a chemical reaction.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):
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