Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
bartleby

Concept explainers

Question
Book Icon
Chapter 28.5, Problem 14P
Interpretation Introduction

Interpretation:

It should explained that why was a deuterated compound used in the given reaction.

Concept introduction:

Pericyclic reactions are “ any concerted reaction in which bonds are formed or brocken in a cyclic transition state”.  There is a single transition state from start to finish, in contrast to a stepwise reaction.

There are mainly three types of pericyclic reactions,

  1. 1) Electrocyclic reactions
  2. 2) Cycloaddition reactions
  3. 3) Sigmatropic reactions

In a sigmatropic reaction “ one new sigma-bond is formed as another breaks.”

Organic Chemistry, Chapter 28.5, Problem 14P

Sigmatropic rearrangement reactions are named with digits.  For example a [1, 3] sigmatropic rearrangement describe a reaction in which the residue migrates from position 1 to position 3.

Blurred answer
Students have asked these similar questions
Pls help asap
Predict the major products of this reaction: ་ ་ + H NaOH ? Δ excess Note that the second reactant is used in excess, that is, there is much more of the second reactant than the first. If there won't be any products, just check the box under the drawing area instead.
P A student claims the right-hand side of the reaction in the drawing area below shows the product of a Claisen condensation. • If the student is correct, complete the reaction by adding the necessary organic reactants to the left-hand side, and by adding any necessary reagents and reaction conditions above and below the arrow. • If the student is incorrect, because it's not possible to obtain this product from a Claisen condensation, check the box under the drawing area instead. those that will minimize any byproducts or competing • Note for advanced students: If you have a choice, use the most efficient reactants and reagents reactions. - ☐ ☐ : ☐ + I Х Click and drag to start drawing a structure.
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning