(a) Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other. Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 1

Question

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

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Answer 2

Question

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 3

Question

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 4

Question

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

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Answer 5

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 6

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 7

Chapter 28, Problem 28.9P

Interpretation Introduction

(a)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 12

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 13

Interpretation Introduction

(d)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 14

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 15

Interpretation Introduction

(e)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 16

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 17

Interpretation Introduction

(f)

Interpretation: The given pair of compounds is to be classified as enantiomers, epimers, diastereomers but not epimers or constitutional isomers of each other.

Concept introduction: Two compounds which are non-superimposable mirror images of each other are known as enantiomers, two compounds which are neither superimposable nor mirror images to each other are known as diastereomers and two compound in which the configuration of one of their stereogenic centers is different are known as epimers.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

Solution Summary: The author explains that D-allose and L-gulose are classified as diastereomers but not epimers.

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