Student Value Bundle: Organic Chemistry, + OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card (NEW!!)

9th Edition

ISBN: 9781305922198

Author: John E. McMurry

Publisher: CENGAGE L

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Chapter 27.SE, Problem 47AP

Cembrene, C₂₀H₃₂, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV absorption at 245 nm, but dihydrocembrene (C₂₀H₃₄), the product of hydrogenation with 1 equivalent of H₂, has no UV absorption. On exhaustive hydrogenation, 4 equivalents of H₂ react, and octahydrocembrene, C₂₀H₄₀, is produced. On ozonolysis of cembrene, followed by treatment of the ozonide with zinc, four carbonylcontaining products are obtained:

Chapter 27.SE, Problem 47AP, Cembrene, C20H32, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV

Propose a structure for cembrene that is consistent with its formation from geranylgeranyl diphosphate.

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Chapter 27.SE, Problem 46AP

Chapter 27.SE, Problem 48AP

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Chapter 27 Solutions

Student Value Bundle: Organic Chemistry, + OWLv2 with Student Solutions Manual eBook, 4 terms (24 months) Printed Access Card (NEW!!)

Ch. 27.1 - Carnauba wax, used in floor and furniture...Ch. 27.1 - Draw structures of glyceryl tripalmitate and...Ch. 27.2 - Prob. 3P Ch. 27.2 - Write the saponication reaction of glyceryl...Ch. 27.4 - Prob. 5P Ch. 27.5 - Prob. 6P Ch. 27.5 - Prob. 7P Ch. 27.6 - Draw the following molecules in chair...Ch. 27.6 - Lithocholic acid is an Aâ€“B cis steroid found in...Ch. 27.7 - Prob. 10P

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