ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 27, Problem 54P
Interpretation Introduction
Interpretation: The structures of the amino acids that form gramicidin S is to be drawn and. The reason corresponding to the fact that the given compound possesses two unusual structural features are to be explained.
Concept introduction: Peptide linkage is formed between the amino group of one amino acid and the carboxyl group of other amino acid with the loss of water molecule. Amino acids are naturally occurring compounds in which the amino group is present on the alpha carbon of carboxyl group. The name of amino acids is represented by the one-letter and three-letter abbreviations.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Propose an efficient synthesis for the following transformation:
EN
The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary
reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct
solution, provide just one answer.
A. t-BuOK
B. Na2Cr2O7, H2SO4, H2O
C. NBS, heat
F. NaCN
D. MeOH
E. NaOH
G. MeONa
H. H2O
I. 1) O3; 2) DMS
Stereochemistry
Identifying the enantiomer of a simple organic molecule
1/5
Check the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of t
above box under the table.
Br
ま
HO
H
0
Molecule 1
Molecule 2
Molecule 3
OH
H
Br
H
H"
Br
OH
Br
Molecule 4
Br
H
OH
+ +
OH
Molecule 5
Br
H
OH
none of the above
Molecule 6
Br
H...
OH
Please answer the questions and provide detailed explanations.
Chapter 27 Solutions
ORGANIC CHEMISTRY BOOK& SG/SM
Ch. 27.1 - Prob. 1PCh. 27.1 - Problem 29.2
What form exists at the isoelectric...Ch. 27.1 - Problem 29.3
Explain why the of the group of an...Ch. 27.1 - Prob. 4PCh. 27.2 - Problem 29.5
What -halo carbonyl compound is...Ch. 27.2 - Problem 29.6
The enolate derived from diethyl...Ch. 27.2 - Problem 29.7
What amino acid is formed when is...Ch. 27.2 - Problem 29.8
What aldehyde is needed to synthesize...Ch. 27.2 - Problem 29.9
Draw the products of each...Ch. 27.3 - Prob. 10P
Ch. 27.3 - Prob. 11PCh. 27.3 - Prob. 12PCh. 27.4 - Problem 29.13
What alkene is needed to synthesize...Ch. 27.5 - Problem 29.14
Draw the structure of each peptide....Ch. 27.5 - Problem 29.15
Name each peptide using both the...Ch. 27 - Draw the product formed when the following amino...Ch. 27 - With reference to the following peptide: a...Ch. 27 - Prob. 31PCh. 27 - Histidine is classified as a basic amino acid...Ch. 27 - Tryptophan is not classified as a basic amino acid...Ch. 27 - What is the structure of each amino acid at its...Ch. 27 - What is the predominant form of each of the...Ch. 27 - 29.37 What is the predominant form of each of the...Ch. 27 - a. Draw the structure of the tripeptide A–A–A, and...Ch. 27 - 29.39 Draw the organic products formed in each...Ch. 27 - 29.40 What alkyl halide is needed to synthesize...Ch. 27 - Prob. 50PCh. 27 - Draw the structure for each peptide: (a) Phe–Ala;...Ch. 27 - 29.52 For the tetrapeptide Asp–Arg–Val–Tyr:
a....Ch. 27 - Prob. 53PCh. 27 - Prob. 54PCh. 27 - 29.55 Draw the amino acids and peptide fragments...Ch. 27 - Prob. 56PCh. 27 - Prob. 57PCh. 27 - Prob. 58PCh. 27 - 29.59 An octapeptide contains the following amino...Ch. 27 - 29.60 Draw the organic products formed in each...Ch. 27 - 29.65 Draw the mechanism for the reaction that...Ch. 27 - 29.66 Which of the following amino acids are...Ch. 27 - 29.67 After the peptide chain of collagen has been...Ch. 27 - Prob. 68PCh. 27 - Prob. 69PCh. 27 - 29.70 The anti-obesity drug orlistat works by...Ch. 27 - Prob. 71P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Question 16 0/1 pts Choose the correct option for the following cycloaddition reaction. C CF3 CF3 CF3 CF3 The reaction is suprafacial/surafacial and forbidden The reaction is antarafacial/antarafacial and forbidden The reaction is antarafacial/antarafacial and allowed The reaction is suprafacial/surafacial and allowedarrow_forward1. Give the structures of the products obtained when the following are heated. Include stereochemistry where relevant. A NO2 + NO2 B + C N=C CEN + { 2. Which compounds would you heat together in order to synthesize the following?arrow_forwardExplain how myo-inositol is different from D-chiro-inositol. use scholarly sources and please hyperlink.arrow_forward
- What is the molarisuty of a 0.396 m glucose solution if its density is 1.16 g/mL? MM glucose 180.2 /mol.arrow_forwardProvide the proper IUPAC or common name for the following compound. Dashes, commas, and spaces must be used correctly. Br ......Im OHarrow_forwardCan you please help me solve this problems. The top one is just drawing out the skeletal correct and then the bottom one is just very confusing to me and its quite small in the images. Can you enlarge it and explain it to me please. Thank You much (ME EX1) Prblm #33arrow_forward
- I'm trying to memorize VESPR Shapes to solve problems like those. I need help making circles like the second image in blue or using an x- and y-axis plane to memorize these and solve those types of problems, especially the ones given in the top/first image (180, 120, 109.5). Can you help me with this? or is their any other efficient method do soarrow_forwardCan you please explain this problems to me? I'm very confused about it. Please provide a detailed, step-by-step explanation for me! (ME EX1) Prblm 27arrow_forwardQuestion 6 of 7 (1 point) | Question Attempt: 1 of 1 = 1 ✓2 ✓ 3 ✓ 4 ✓ 5 6 ✓ 7 This organic molecule is dissolved in a basic aqueous solution: Jen ✓ ? A short time later sensitive infrared spectroscopy reveals the presence of a new C-OH stretch absorption. That is, must now be a new molecule present with at least one C- OH bond. there 18 In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule Ar © + Click and drag to start drawing a structure. Add/Remove step Click and drawing Save For Later Submit Assignmentarrow_forward
- Can you please explain this problem to me? I'm very confused about it. Please provide a detailed, step-by-step explanation for me! (ME EX1) Prblm 22arrow_forwardCan you please explain this problems to me? I'm very confused about it. Please provide a detailed, step-by-step explanation for me! (ME EX1) Prblm 30arrow_forwardThis organic molecule is dissolved in a basic aqueous solution: O ? olo RET A short time later sensitive infrared spectroscopy reveals the presence of a new C-OH stretch absorption. That is, there Ar must now be a new molecule present with at least one C - OH bond. In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule. $ Add/Remove steparrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning