Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide
Organic Chemistry Third Edition + Electronic Solutions Manual And Study Guide
3rd Edition
ISBN: 9781119351610
Author: David Klein
Publisher: Wiley Plus
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Chapter 27, Problem 35PP
Interpretation Introduction

Interpretation:

Vinyl shower curtains cracks over time need to be explained.

Concept introduction:

Thermoplastic polymers are a type of polymer which is hard at room temperature but soft when the temperature is increased.  The thermoplastics are very useful as it can be molded and converted into other shapes when the temperature is increased.

Plasticizers are small molecules that are added to the polymer to prevent cracking at room temperature.  These plasticizers are trapped between the polymers.

To explain: why vinyl shower develop cracks over time.

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
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