Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 27, Problem 27.57P
Interpretation Introduction

Interpretation: The mechanism for the given Carroll rearrangement reaction is to be drawn.

Concept introduction: Carroll rearrangement is a reaction in which βketo ester reacts with allylic alcohol in the presence of base to give unsaturated carbonyl compound.

In the sigmatropic rearrangement, the rearrangement of pi bond and the breaking of sigma bond take place. This results in the generation of new sigma bond in the product. In this type of rearrangement, the number of pi bonds remains constant in the reactant as well as in the product.

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