Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
Question
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Chapter 27, Problem 27.16P
Interpretation Introduction

(a)

Interpretation: The product formed in the given cycloaddition reaction is to be drawn.

Concept introduction: Diels-Alder reactions are the chemical reactions in which diene and dienophile participate to form Diels-Alder adduct. The rate of reaction is fast when the electronegative group is attached to dienophile.

Interpretation Introduction

(b)

Interpretation: The product formed in the given cycloaddition reaction is to be drawn.

Concept introduction: Diels-Alder reactions are the chemical reactions in which diene and dienophile participate to form Diels-Alder adduct. The rate of reaction is fast when the electronegative group is attached to dienophile.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):
1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):
(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

Chapter 27 Solutions

Organic Chemistry

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