Principles of Instrumental Analysis, 6th Edition
6th Edition
ISBN: 9788131525579
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cenage Learning
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Question
Chapter 27, Problem 27.24QAP
Interpretation Introduction
Interpretation:
The reason and the change in the retention times for the three compounds is to be stated.
Concept introduction:
Retention time is the amount of time that arises in between the sample introduction and the maximum of the response. It is the time taken by the solute to completely pass through the column. The retention time is less for non-polar solvents, whereas it is relatively large for polar solvents.
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What are the IUPAC Names of all the compounds in the picture?
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roadmaps along with your new Chapter 19 roadmap for these.
(a)
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3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
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Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
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5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
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Chapter 27 Solutions
Principles of Instrumental Analysis, 6th Edition
Ch. 27 - Prob. 27.1QAPCh. 27 - Prob. 27.2QAPCh. 27 - Prob. 27.3QAPCh. 27 - Prob. 27.4QAPCh. 27 - Prob. 27.5QAPCh. 27 - Prob. 27.6QAPCh. 27 - Prob. 27.7QAPCh. 27 - Prob. 27.8QAPCh. 27 - Prob. 27.9QAPCh. 27 - What are hyphenated GC methods? Briefly describe...
Ch. 27 - Prob. 27.11QAPCh. 27 - Prob. 27.12QAPCh. 27 - Prob. 27.13QAPCh. 27 - Prob. 27.14QAPCh. 27 - Prob. 27.15QAPCh. 27 - Prob. 27.16QAPCh. 27 - Prob. 27.17QAPCh. 27 - Prob. 27.18QAPCh. 27 - Prob. 27.19QAPCh. 27 - The same polar compound is gas chromatographed on...Ch. 27 - Prob. 27.21QAPCh. 27 - Prob. 27.22QAPCh. 27 - Prob. 27.23QAPCh. 27 - Prob. 27.24QAPCh. 27 - Prob. 27.25QAPCh. 27 - Prob. 27.26QAPCh. 27 - Prob. 27.27QAPCh. 27 - Prob. 27.28QAPCh. 27 - Why is GSC not used nearly as extensively as GLC?Ch. 27 - Prob. 27.30QAP
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