(a)
Interpretation:
Chemical structure of the
Concept introduction:
Any polymer can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). Naming of polymer is based on the monomer from which it was derived.
If the monomer contains only one word in the name then no parenthesis is used when naming polymer but if the monomer contains two words means parenthesis is used around the name of monomer.
Monomer with two words=poly(monomer)
Monomer with single word=poly-monomer
(a)
Answer to Problem 22PP
The polymer is polynitroethylene and the structure is
Explanation of Solution
To draw and name the polymer when vinyl acetate undergoes polymerization
Draw the structure of nitroethylene
The structure of nitroethylene is drawn following
Polymerization of nitroethylene
The nitroethylene has a double bond which can involve in polymerization with another nitroethylene which propogates to the other molecules to form a chain where the repeating unit is the monomer unit without a double bond as it is involved in polymerization. nitroethylene polymerizes to form polynitroethylene
(b)
Interpretation:
Chemical structure of the polymer should be drawn and named when given monomer undergoes polymerization.
Concept introduction:
Any polymer can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). Naming of polymer is based on the monomer from which it was derived.
If the monomer contains only one word in the name then no parenthesis is used when naming polymer but if the monomer contains two words means parenthesis is used around the name of monomer.
Monomer with two words=poly(monomer)
Monomer with single word=poly-monomer
(b)
Answer to Problem 22PP
The polymer is polyacrylonitrile and the structure is
Explanation of Solution
To draw and name the polymer when acrylonitrile undergoes polymerization
Draw the structure of acrylonitrile
The structure of acrylonitrile is drawn following IUPAC nomenclature.
Polymerization of acrylonitrile
The acrylonitrile has a double bond which can involve in polymerization with another acrylonitrile which propogates to the other molecules to form a chain where the repeating unit is the monomer unit without a double bond as it is involved in polymerization. Acrylonitrile polymerizes to form polyacrylonitrile.
(c)
Interpretation:
Chemical structure of the polymer should be drawn and named when given monomer undergoes polymerization.
Concept introduction:
Any polymer can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). Naming of polymer is based on the monomer from which it was derived.
If the monomer contains only one word in the name then no parenthesis is used when naming polymer but if the monomer contains two words means parenthesis is used around the name of monomer.
Monomer with two words=poly(monomer)
Monomer with single word=poly-monomer
(c)
Answer to Problem 22PP
The polymer is poly(vinylidene fluoride) and the structure is
Explanation of Solution
To draw and name the polymer when vinylidene fluoride undergoes polymerization
Draw the structure of vinylidene fluoride
The structure of vinylidene fluoride is drawn following IUPAC nomenclature.
Polymerization of vinylidene fluoride
The vinylidene fluoride has a double bond which can involve in polymerization with another vinylidene fluoride which propogates to the other molecules to form a chain where the repeating unit is the monomer unit without a double bond as it is involved in polymerization. vinylidene fluoride polymerizes to form poly(vinylidene fluoride). As this monomer has two words in its name the polymer is named with paranthesis
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Chapter 27 Solutions
ORGANIC CHEMISTRY LL PRINT UPGRADE
- true or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 5. 4NO2(g) ⇔ 2N2O4(g)arrow_forwardtrue or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 0.4. 2N2O4(g) ⇔ 4NO2(g)arrow_forwardtrue or false Using the following equilibrium, if heat is added the equilibrium will shift toward the reactants. N2(g) + 3H2(g) ⇔ 2NH3(g) + heatarrow_forward
- True or False Using the following equilibrium, if heat is added the equilibrium will shift toward the products. N2O4(g) + heat ⇔ 2NO2(g)arrow_forwardtrue or false Using the following equilibrium, if solid carbon is added the equilibrium will shift toward the products. C(s) + CO2(g) ⇔ 2CO(g)arrow_forwardProvide the complete mechanism for the reaction below. You must include appropriate arrows,intermediates, and formal charges. Please also provide a reason to explain why the 1,4-adduct is preferred over the 1,3-adduct.arrow_forward
- Which of the following pairs are resonance structures of one another? I. III. || III IV + II. :0: n P !༠ IV. EN: Narrow_forwardPredict the major organic product(s) and byproducts (either organic or inorganic) for thefollowing reactions.arrow_forwardA 8.25 g sample of aluminum at 55°C released 2500 J of heat. The specific heat of aluminum is 0.900 J/g°C. The density of aluminum is 2.70 g/mL. Calculate the final temperature of the aluminum sample in °C.arrow_forward
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