Para-methoxystyrene undergoes cationic polymerization more rapidly than meta-methoxystyrene need to be explained. Concept introduction: Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways, Cationic polymerization Radical polymerization Anionic polymerization Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups . In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules. If the electron donating group is present in the ortho or para position it stabilizes the formed positive charge than the same group present in meta position. Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron-withdrawing groups (electronegative groups). In this polymerization carbanion is the active species. Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals. To explain : To explain why para-methoxystyrene undergoes cationic polymerization rapidly than meta-methoxystyrene

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Answer 1

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27, Problem 40PP

Interpretation Introduction

Interpretation:

Para-methoxystyrene undergoes cationic polymerization more rapidly than meta-methoxystyrene need to be explained.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,

Cationic polymerization

Radical polymerization

Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules. If the electron donating group is present in the ortho or para position it stabilizes the formed positive charge than the same group present in meta position.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron-withdrawing groups (electronegative groups). In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To explain: To explain why para-methoxystyrene undergoes cationic polymerization rapidly than meta-methoxystyrene

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What is the reaction mechanism for this? Can this even be done without a base?

Answer 2

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27, Problem 40PP

Interpretation Introduction

Interpretation:

Para-methoxystyrene undergoes cationic polymerization more rapidly than meta-methoxystyrene need to be explained.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,

Cationic polymerization

Radical polymerization

Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules. If the electron donating group is present in the ortho or para position it stabilizes the formed positive charge than the same group present in meta position.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron-withdrawing groups (electronegative groups). In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To explain: To explain why para-methoxystyrene undergoes cationic polymerization rapidly than meta-methoxystyrene

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27, Problem 40PP

Interpretation Introduction

Interpretation:

Para-methoxystyrene undergoes cationic polymerization more rapidly than meta-methoxystyrene need to be explained.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain. Polymerization can occur via three ways,

Cationic polymerization

Radical polymerization

Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules. If the electron donating group is present in the ortho or para position it stabilizes the formed positive charge than the same group present in meta position.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron-withdrawing groups (electronegative groups). In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To explain: To explain why para-methoxystyrene undergoes cationic polymerization rapidly than meta-methoxystyrene

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27, Problem 40PP

Interpretation Introduction