Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 26.3, Problem 6ATS

(a)

Interpretation Introduction

Interpretation:

The given set of triglycerides is fat or oil need to be identified.

Concept introduction:

Melting point of a compound is the temperature at which the compound starts to change from solid state to liquid state when temperature is raised.  The total number of carbon atoms determines the melting point of the compound.  Higher the carbon atoms and no unsaturation means higher is the melting point.  If the melting point is low then the triglyceride will be in form of oil and if the melting point is high then the triglyceride will be fat.  The generic structure of triglyceride can be drawn as,

Organic Chemistry, Binder Ready Version, Chapter 26.3, Problem 6ATS , additional homework tip  1

To identify: the triglyceride containing one palmitic acid and two stearic acid residues as fat or oil.

(b)

Interpretation Introduction

Interpretation:

The given set of triglycerides is fat or oil need to be identified.

Concept introduction:

Melting point of a compound is the temperature at which the compound starts to change from solid state to liquid state when temperature is raised.  The total number of carbon atoms determines the melting point of the compound.  Higher the carbon atoms and no unsaturation means higher is the melting point.  If the melting point is low then the triglyceride will be in form of oil and if the melting point is high then the triglyceride will be fat.  The generic structure of triglyceride can be drawn as,

Organic Chemistry, Binder Ready Version, Chapter 26.3, Problem 6ATS , additional homework tip  2

To identify: the triglyceride containing one oleic acid and two linoleic acid residues as fat or oil.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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