Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 26, Problem 49DSP
Interpretation Introduction
Interpretation:
The carbon atom of L-glutamic acid, which is involved in the only carbon-carbon bond forming step of the synthesis given, is to be determined.
Concept introduction:
Natural L-glutamic acid has S configuration. If no reaction takes places at the chiral carbon atom of the amino acid, then its configuration is retained in the products formed.
The alpha carbon atom in the amino acid is attached to a nitrogen atom, the carboxyl carbon, and one other carbon atom.
Tracing the carbon atoms of the amino acid in the product, the carbon atoms of the amino acid in the product can be identified.
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Predict the product of this organic reaction:
IZ
+
HO
i
P+H₂O
Specifically, in the drawing area below draw the skeletal ("line") structure of P.
If there is no reasonable possibility for P, check the No answer box under the drawing area.
No Answer
Click and drag to start drawing a
structure.
☐ :
Predict the products of this organic reaction:
0
O
-----
A
+ KOH ?
CH3-CH2-C-O-CH2-C-CH3
Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them
in any arrangement you like, so long as they aren't touching.)
If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area.
No reaction
Click anywhere to draw the first
atom of your structure.
X
⑤
è
Chapter 26 Solutions
Organic Chemistry - Standalone book
Ch. 26.1 - Prob. 1PCh. 26.2 - Prob. 2PCh. 26.2 - Prob. 3PCh. 26.3 - Prob. 4PCh. 26.3 - Prob. 5PCh. 26.4 - Prob. 6PCh. 26.4 - Prob. 7PCh. 26.4 - Prob. 8PCh. 26.5 - Prob. 9PCh. 26.6 - Prob. 10P
Ch. 26.6 - Prob. 11PCh. 26.6 - Prob. 12PCh. 26.7 - Prob. 13PCh. 26.7 - Prob. 14PCh. 26.7 - Prob. 15PCh. 26.7 - Prob. 16PCh. 26.7 - Prob. 17PCh. 26.9 - Prob. 18PCh. 26.10 - Digestion of the tetrapeptide of Problem 26.18...Ch. 26.12 - Prob. 20PCh. 26.12 - Prob. 21PCh. 26.15 - Prob. 22PCh. 26.15 - Prob. 23PCh. 26.16 - Prob. 24PCh. 26.17 - Prob. 25PCh. 26.18 - Prob. 26PCh. 26 - Prob. 27PCh. 26 - Prob. 28PCh. 26 - Prob. 29PCh. 26 - Prob. 30PCh. 26 - Prob. 31PCh. 26 - Prob. 32PCh. 26 - Prob. 33PCh. 26 - Prob. 34PCh. 26 - Prob. 35PCh. 26 - Prob. 36PCh. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - Prob. 39PCh. 26 - Prob. 40PCh. 26 - If you synthesized the tripeptide Leu-Phe-Ser from...Ch. 26 - Prob. 42PCh. 26 - Prob. 43PCh. 26 - Prob. 44PCh. 26 - Prob. 45DSPCh. 26 - Prob. 46DSPCh. 26 - Prob. 47DSPCh. 26 - Prob. 48DSPCh. 26 - Prob. 49DSPCh. 26 - Prob. 50DSP
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