ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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Chapter 26, Problem 37P
Interpretation Introduction

(a)

Interpretation: The given cyclic monosaccharide is to be converted into a Fischer projection of its acyclic form.

Concept introduction: In the Fisher projection formula, a stereogenic centre is located at intersection of the two lines. The horizontal and vertical bonds are denoted by wedges and dashed wedges.

Interpretation Introduction

(b)

Interpretation: The name of the given monosaccharide is to be predicted.

Concept introduction: The anomers are cyclic monosaccharides which are differ in configuration at C1 in aldoses and at C2 in ketoses. These carbon atoms are called anomeric centre.

Interpretation Introduction

(c)

Interpretation: The anomer of given monosaccharide is to be labeled as α or β.

Concept introduction: The anomers are cyclic monosaccharides which are differ in configuration at C1 in aldoses and at C2 in ketoses. These carbon atoms are called anomeric centre. The anomeric centre is labeled by α or β.

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Chapter 26 Solutions

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