Get Ready for Organic Chemistry
Get Ready for Organic Chemistry
2nd Edition
ISBN: 9780321774125
Author: KARTY, Joel
Publisher: PEARSON
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Chapter 26, Problem 26.9YT
Interpretation Introduction

Interpretation:

Combination and disproportionation are not feasible termination steps for the anionic polymerization of styrene. The reason is to be explained.

Concept introduction:

Beside the free-radical mechanism, chain-growth polymerizations can also be initiated by anions or cations, resulting in anionic polymerization or cationic polymerization respectively. Styrene can undergo anionic polymerization using butyllithium as the initiator, which forms a negative charge on the growing chain instead of an unpaired electron. In the propagation steps, the reactive intermediates are anions. Termination occurs in anionic polymerization when an acid is added to the reaction mixture. The anion is neutralized in the resulting proton transfer, which ends the propagation cycle. Combination and disproportionation are not feasible termination steps for the anionic polymerization of styrene.

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Chapter 26 Solutions

Get Ready for Organic Chemistry

Ch. 26 - Prob. 26.11PCh. 26 - Prob. 26.12PCh. 26 - Prob. 26.13PCh. 26 - Prob. 26.14PCh. 26 - Prob. 26.15PCh. 26 - Prob. 26.16PCh. 26 - Prob. 26.17PCh. 26 - Prob. 26.18PCh. 26 - Prob. 26.19PCh. 26 - Prob. 26.20PCh. 26 - Prob. 26.21PCh. 26 - Prob. 26.22PCh. 26 - Prob. 26.23PCh. 26 - Prob. 26.24PCh. 26 - Prob. 26.25PCh. 26 - Prob. 26.26PCh. 26 - Prob. 26.27PCh. 26 - Prob. 26.28PCh. 26 - Prob. 26.29PCh. 26 - Prob. 26.30PCh. 26 - Prob. 26.31PCh. 26 - Prob. 26.32PCh. 26 - Prob. 26.33PCh. 26 - Prob. 26.34PCh. 26 - Prob. 26.35PCh. 26 - Prob. 26.36PCh. 26 - Prob. 26.37PCh. 26 - Prob. 26.38PCh. 26 - Prob. 26.39PCh. 26 - Prob. 26.40PCh. 26 - Prob. 26.41PCh. 26 - Prob. 26.42PCh. 26 - Prob. 26.43PCh. 26 - Prob. 26.44PCh. 26 - Prob. 26.45PCh. 26 - Prob. 26.46PCh. 26 - Prob. 26.47PCh. 26 - Prob. 26.48PCh. 26 - Prob. 26.49PCh. 26 - Prob. 26.50PCh. 26 - Prob. 26.51PCh. 26 - Prob. 26.52PCh. 26 - Prob. 26.53PCh. 26 - Prob. 26.54PCh. 26 - Prob. 26.55PCh. 26 - Prob. 26.56PCh. 26 - Prob. 26.57PCh. 26 - Prob. 26.58PCh. 26 - Prob. 26.59PCh. 26 - Prob. 26.60PCh. 26 - Prob. 26.61PCh. 26 - Prob. 26.62PCh. 26 - Prob. 26.63PCh. 26 - Prob. 26.64PCh. 26 - Prob. 26.65PCh. 26 - Prob. 26.66PCh. 26 - Prob. 26.67PCh. 26 - Prob. 26.68PCh. 26 - Prob. 26.69PCh. 26 - Prob. 26.70PCh. 26 - Prob. 26.71PCh. 26 - Prob. 26.72PCh. 26 - Prob. 26.73PCh. 26 - Prob. 26.74PCh. 26 - Prob. 26.75PCh. 26 - Prob. 26.76PCh. 26 - Prob. 26.77PCh. 26 - Prob. 26.78PCh. 26 - Prob. 26.1YTCh. 26 - Prob. 26.2YTCh. 26 - Prob. 26.3YTCh. 26 - Prob. 26.4YTCh. 26 - Prob. 26.5YTCh. 26 - Prob. 26.6YTCh. 26 - Prob. 26.7YTCh. 26 - Prob. 26.8YTCh. 26 - Prob. 26.9YTCh. 26 - Prob. 26.10YTCh. 26 - Prob. 26.11YTCh. 26 - Prob. 26.12YTCh. 26 - Prob. 26.13YTCh. 26 - Prob. 26.14YTCh. 26 - Prob. 26.15YTCh. 26 - Prob. 26.16YTCh. 26 - Prob. 26.17YTCh. 26 - Prob. 26.18YTCh. 26 - Prob. 26.19YTCh. 26 - Prob. 26.20YTCh. 26 - Prob. 26.21YTCh. 26 - Prob. 26.22YTCh. 26 - Prob. 26.23YT
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