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Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 26, Problem 26.52QP
In basic solution, aluminum metal is a strong reducing agent and is oxidized to AlO2− Give balanced equations for the reaction of Al m basic solution with the following: (a) NaNO3, to give ammonia, (b) water, to give hydrogen; (c) Na2SnO3, to give metallic tin.
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
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F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
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Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
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LL
F
C
D
OH
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LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 26 Solutions
Chemistry: Atoms First
Ch. 26 - Prob. 26.1QPCh. 26 - Prob. 26.2QPCh. 26 - Prob. 26.3QPCh. 26 - Prob. 26.4QPCh. 26 - Prob. 26.5QPCh. 26 - Prob. 26.6QPCh. 26 - Prob. 26.7QPCh. 26 - Describe with examples the chemical and...Ch. 26 - Prob. 26.9QPCh. 26 - Prob. 26.10QP
Ch. 26 - Prob. 26.11QPCh. 26 - Prob. 26.12QPCh. 26 - Prob. 26.13QPCh. 26 - Prob. 26.14QPCh. 26 - Prob. 26.15QPCh. 26 - Prob. 26.16QPCh. 26 - Prob. 26.17QPCh. 26 - Prob. 26.18QPCh. 26 - Which of the following compounds would require...Ch. 26 - Prob. 26.20QPCh. 26 - Prob. 26.21QPCh. 26 - Prob. 26.22QPCh. 26 - Prob. 26.23QPCh. 26 - Prob. 26.24QPCh. 26 - Prob. 26.25QPCh. 26 - Prob. 26.26QPCh. 26 - Prob. 26.27QPCh. 26 - Prob. 26.28QPCh. 26 - Prob. 26.29QPCh. 26 - Prob. 26.30QPCh. 26 - Prob. 26.31QPCh. 26 - Prob. 26.32QPCh. 26 - Prob. 26.33QPCh. 26 - Prob. 26.34QPCh. 26 - Prob. 26.35QPCh. 26 - Prob. 26.36QPCh. 26 - Prob. 26.37QPCh. 26 - Prob. 26.38QPCh. 26 - Prob. 26.39QPCh. 26 - Prob. 26.40QPCh. 26 - Prob. 26.41QPCh. 26 - Prob. 26.42QPCh. 26 - Prob. 26.43QPCh. 26 - Prob. 26.44QPCh. 26 - Prob. 26.45QPCh. 26 - Prob. 26.46QPCh. 26 - Prob. 26.47QPCh. 26 - With the Hall process, how many hours will it take...Ch. 26 - The overall reaction for the electrolytic...Ch. 26 - Prob. 26.50QPCh. 26 - Prob. 26.51QPCh. 26 - In basic solution, aluminum metal is a strong...Ch. 26 - Prob. 26.53QPCh. 26 - Prob. 26.54QPCh. 26 - Prob. 26.55QPCh. 26 - Prob. 26.56QPCh. 26 - Prob. 26.57QPCh. 26 - Prob. 26.58QPCh. 26 - Prob. 26.59QPCh. 26 - Prob. 26.60QPCh. 26 - Prob. 26.61QPCh. 26 - Prob. 26.62QPCh. 26 - Prob. 26.63QPCh. 26 - Prob. 26.64QPCh. 26 - Prob. 26.65QPCh. 26 - Prob. 26.66QPCh. 26 - Prob. 26.67QPCh. 26 - Prob. 26.68QPCh. 26 - Prob. 26.69QPCh. 26 - Prob. 26.70QPCh. 26 - Prob. 26.71QPCh. 26 - Prob. 26.72QPCh. 26 - Prob. 26.73QPCh. 26 - The following are two reaction schemes involving...Ch. 26 - Prob. 26.75QPCh. 26 - Prob. 26.76QPCh. 26 - Prob. 26.77QPCh. 26 - Prob. 26.78QPCh. 26 - Prob. 26.79QPCh. 26 - Prob. 26.80QPCh. 26 - Prob. 26.81QPCh. 26 - Chemical tests of four metals A, B, C, and D show...
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
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