Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 26, Problem 24P
Interpretation Introduction
Interpretation:
The compound formed by the reaction of coenzyme A with acetate is to be determined.
Concept introduction:
The CoA is used for the oxidation of fatty acid and pyruvate. It is synthesized from the vitamin
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 26 Solutions
Introduction to General, Organic and Biochemistry
Ch. 26.1 - Prob. 26.1QCCh. 26.2 - Prob. 26.2QCCh. 26.3 - Prob. 26.3QCCh. 26.4 - Prob. 26.4QCCh. 26.5 - Prob. 26.5QCCh. 26.6 - Prob. 26.6QCCh. 26.7 - Prob. 26.7QCCh. 26.8 - Prob. 26.8QCCh. 26 - Prob. 1PCh. 26 - Prob. 2P
Ch. 26 - Prob. 3PCh. 26 - Prob. 4PCh. 26 - Prob. 5PCh. 26 - Prob. 6PCh. 26 - (a) How many membranes do mitochondria have? (b)...Ch. 26 - Prob. 8PCh. 26 - Prob. 9PCh. 26 - Prob. 10PCh. 26 - Prob. 11PCh. 26 - Prob. 12PCh. 26 - Prob. 13PCh. 26 - Prob. 14PCh. 26 - What kind of chemical bond exists between the...Ch. 26 - Prob. 16PCh. 26 - Which atoms in the flavin portion of FAD are...Ch. 26 - NAD+ has two ribose units in its structure; FAD...Ch. 26 - Prob. 19PCh. 26 - The ribitol in FAD is bound to phosphate. What is...Ch. 26 - What kind Of chemical bond exists between the...Ch. 26 - Prob. 22PCh. 26 - Prob. 23PCh. 26 - Prob. 24PCh. 26 - Prob. 25PCh. 26 - Prob. 26PCh. 26 - Prob. 27PCh. 26 - Prob. 28PCh. 26 - Prob. 29PCh. 26 - Prob. 30PCh. 26 - Prob. 31PCh. 26 - Prob. 32PCh. 26 - Prob. 33PCh. 26 - Prob. 34PCh. 26 - Prob. 35PCh. 26 - Prob. 36PCh. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - Prob. 39PCh. 26 - Prob. 40PCh. 26 - Prob. 41PCh. 26 - Prob. 42PCh. 26 - Prob. 43PCh. 26 - Prob. 44PCh. 26 - Prob. 45PCh. 26 - Prob. 46PCh. 26 - Prob. 47PCh. 26 - Prob. 48PCh. 26 - Prob. 49PCh. 26 - Prob. 50PCh. 26 - Prob. 51PCh. 26 - Prob. 52PCh. 26 - Prob. 53PCh. 26 - A hexose (C6) enters the common metabolic pathway...Ch. 26 - Prob. 55PCh. 26 - Prob. 56PCh. 26 - Prob. 57PCh. 26 - Prob. 58PCh. 26 - Prob. 59PCh. 26 - Prob. 60PCh. 26 - Prob. 61PCh. 26 - Prob. 62PCh. 26 - Prob. 63PCh. 26 - Prob. 64PCh. 26 - Prob. 65PCh. 26 - Prob. 66PCh. 26 - Prob. 67PCh. 26 - Prob. 68PCh. 26 - Prob. 69PCh. 26 - What is the basic difference in the functional...Ch. 26 - Prob. 71PCh. 26 - Prob. 72PCh. 26 - Prob. 73PCh. 26 - Prob. 74PCh. 26 - Prob. 75PCh. 26 - Prob. 76PCh. 26 - Prob. 77PCh. 26 - Prob. 78PCh. 26 - Prob. 79PCh. 26 - Prob. 80PCh. 26 - Prob. 81PCh. 26 - Prob. 82PCh. 26 - Prob. 83PCh. 26 - Prob. 84PCh. 26 - Prob. 85PCh. 26 - Prob. 86PCh. 26 - Some soft drinks contain citric acid as flavoring....Ch. 26 - Prob. 88PCh. 26 - Prob. 89PCh. 26 - Prob. 90PCh. 26 - Prob. 91PCh. 26 - Prob. 92PCh. 26 - Prob. 93PCh. 26 - Prob. 94PCh. 26 - Prob. 95PCh. 26 - Prob. 96PCh. 26 - Prob. 97PCh. 26 - Why is it somewhat misleading to study biochemi-...Ch. 26 - Prob. 99PCh. 26 - Prob. 100PCh. 26 - Prob. 101PCh. 26 - Prob. 102PCh. 26 - Prob. 103PCh. 26 - Prob. 104PCh. 26 - Prob. 105PCh. 26 - Prob. 106PCh. 26 - Prob. 107PCh. 26 - Prob. 108PCh. 26 - Prob. 109PCh. 26 - Prob. 110PCh. 26 - Prob. 111PCh. 26 - Prob. 112P
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