EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
9th Edition
ISBN: 9780100591318
Author: McMurry
Publisher: YUZU
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Chapter 25.SE, Problem 43AP
Interpretation Introduction

Interpretation:

Fischer projections for two D-aldoheptoses whose stereochemistry at C3, C4, C5 and C6 is the same as that of D-glucose at C2, C3, C4 and C5 are to be drawn.

Concept introduction:

When a new chiral center is created in an optically active monosaccharide molecule the arrangement of H and OH on the new chiral center can be either H at left and OH at right or H at right and OH at left. Hence two isomers can be written.

To draw:

Fischer projections for two D-aldoheptoses whose stereochemistry at C3, C4, C5 and C6 is the same as that of D-glucose at C2, C3, C4 and C5.

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43) 10.00 ml of vinegar (active ingredient is acetic acid) is titrated to the endpoint using 19.32 ml of 0.250 M sodium hydroxide. What is the molarity of acetic acid in the vinegar? YOU MUST SHOW YOUR WORK. NOTE: MA x VA = MB x VB
424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
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Chapter 25 Solutions

EBK ORGANIC CHEMISTRY

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