The possible products formed in the electrophilic substitution of chlorobenzene with bisulfite ion are to be shown. Concept introduction: Substitution reaction involves the replacement of a group by another group of the same type. Substitution reactions are of two types, electrophilic substitution, in which an electrophile substitutes another electrophile, and nucleophilic substitution, in which a nucleophile substitutes another nucleophile. The replacement of a proton by electrophile in aromatic compounds is an example of electrophilic substitution reaction. It involves the addition of electrophile on one of the pi bonds of aromatic system followed by the resonance stabilization of the generated carbocation. Then, in the last step, the proton gets eliminated and the pi bonded system is restored. If the aromatic ring is already substituted, then the incoming group gets attached at either ortho (position adjacent to already existing group), meta (position next to adjacent of already existing group) or para (position opposite to already existing group) positions depending on the nature of both the groups.

Question

Want to see the full answer?

Answer 1

Question

Chapter 25.5, Problem 1PPB

Interpretation Introduction

Interpretation:

The possible products formed in the electrophilic substitution of chlorobenzene with bisulfite ion are to be shown.

Concept introduction:

Substitution reaction involves the replacement of a group by another group of the same type.

Substitution reactions are of two types, electrophilic substitution, in which an electrophile substitutes another electrophile, and nucleophilic substitution, in which a nucleophile substitutes another nucleophile.

The replacement of a proton by electrophile in aromatic compounds is an example of electrophilic substitution reaction. It involves the addition of electrophile on one of the pi bonds of aromatic system followed by the resonance stabilization of the generated carbocation. Then, in the last step, the proton gets eliminated and the pi bonded system is restored.

If the aromatic ring is already substituted, then the incoming group gets attached at either ortho (position adjacent to already existing group), meta (position next to adjacent of already existing group) or para (position opposite to already existing group) positions depending on the nature of both the groups.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

In the spectroscopic technique known as photoelectron spectroscopy (PES), ultraviolet radiation is directed at an atom or molecule. Electrons are ejected from the valence shell and their kinetic energies are measured. Since the energy of the incident ultraviolet photons is known and the kinetic energy of the ejected electron is measured, the ionization energy, I, can be deduced because total energy is conserved. (a) Show that the velocity, v, of the ejected electron and the frequency, n, of the incident radiation are related by hv = I + (1/2)mv^2? (b) Use this relation to calculate the ionization energy of a rubidium atom, knowing that light of wavelength 58.4 nm produces electrons with a velocity of 2,450 km/s Recall that 1 J = 1 kg.m^2/s^2

I) In Millikan's experiment, each droplet observed by the technicians contained an even number of electrons. If they had been unaware of this limitation, how would it have affected their report of an electron's charge?II) Millikan measured the charge of an electron in electrostatic units, esu. The data he collected included the following series of charges found on oil drops: 9.60 X 10^-10 esu, 1.92 X 10^-9 esu; 2.40 X 10^-9 esu; 2.88 X 10^-9 esu; and 4.80 X 10^-9 esu. (a) From this series, find the probable charge of the electron in electrostatic units. (b) Estimate the number of electrons in an oil drop with a charge of 6.72 X 10^-9 esu. The actual charge (in Coulombs) of an electron is 1.602 X 10^-19 C. What is the relationship between esu and Coulombs?

my ccc edu - Search X Quick Access X D2L Homepage - Spring 2025 x N Netflix X Dimensional Analysis - A x+ pp.aktiv.com Q ☆ X Question 59 of 70 The volume of 1 unit of plasma is 200.0 mL If the recommended dosage for adult patients is 10.0 mL per kg of body mass, how many units are needed for a patient with a body mass of 80.0 kg ? 80.0 kg 10.0 DAL 1 units X X 4.00 units 1 1 Jeg 200.0 DAL L 1 units X 200.0 mL = 4.00 units ADD FACTOR *( ) DELETE ANSWER RESET D 200.0 2.00 1.60 × 10³ 80.0 4.00 0.0400 0.250 10.0 8.00 & mL mL/kg kg units/mL L unit Q Search delete prt sc 111 110 19