
Concept explainers
Interpretation:
The structural formula for the compounds based on their systematic names is to be written.
Concept introduction:
The structural formula is the formula thatprovides an insight into the structure of the compound. It shows all the substituents and
The structure can be easily written from the systematic name. The parent chain is at first drawn and then it is numbered from any end. The substituents can be written on those numbers bearing carbon in the parent chain.
Thereafter, the name is written, which includes the name of the substituent and the number of substituents. The substituents are written with their number in alphabetical order, followed by the name of the parent chain and the functional group as a suffix.
The suffix –olis used for the alcohol group.
The suffix –al is used for the aldehyde group.
The suffix –one is used for the ketone group.
The –e ending of an
The suffix amide is then added for the amide group.
The suffix -oate is used for the ester.
Functional groups are specific substituent within the molecules that are responsible for the characteristic
Esters are the organic compounds thatcontain
Alcohols are the organic compounds thatcontain
Amides are the organic compounds thatcontain

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Chapter 25 Solutions
Chemistry
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- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
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