EBK ORGANIC CHEMISTRY
9th Edition
ISBN: 8220102744097
Author: SIMEK
Publisher: PEARSON
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Question
Chapter 25.4, Problem 25.6P
Interpretation Introduction
Interpretation: The hydrophilic and hydrophobic regions in the structure of benzalkonium chloride, Nonoxynol and Gardol are to be predicted.
Concept introduction: The hydrophilic parts are mostly long chain hydrocarbons which are soluble in polar solvents but insoluble in non-polar solvents, whereas hydrophobic parts are soluble in non-polar solvents.
To determine: The hydrophilic and hydrophobic regions in the structure of benzalkonium chloride, Nonoxynol and Gardol.
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 25 Solutions
EBK ORGANIC CHEMISTRY
Ch. 25.3 - Prob. 25.1PCh. 25.3A - Prob. 25.2PCh. 25.3B - Give an equaton for the complete transestenfcation...Ch. 25.4 - Prob. 25.4PCh. 25.4 - Several commercial laundry soaps contain...Ch. 25.4 - Prob. 25.6PCh. 25.4 - Prob. 25.7PCh. 25.5 - Prob. 25.8PCh. 25.6 - How would you use a simple extraction to separate...Ch. 25.6 - Prob. 25.10P
Ch. 25.8A - Circle the isoprene units in geranial, menthol,...Ch. 25.8B - Prob. 25.12PCh. 25.8B - Prob. 25.13PCh. 25 - Prob. 25.14SPCh. 25 - Prob. 25.15SPCh. 25 - Show how you would convert oleic acid to the...Ch. 25 - Give the general classification of each compound....Ch. 25 - Phospholipids undergo saponification much like...Ch. 25 - Prob. 25.19SPCh. 25 - Prob. 25.20SPCh. 25 - Prob. 25.21SPCh. 25 - Prob. 25.22SPCh. 25 - Prob. 25.23SPCh. 25 - The structure of limonene appears in Problem25-13....Ch. 25 - Prob. 25.25SPCh. 25 - Prob. 25.26SPCh. 25 - Prob. 25.27SPCh. 25 - Prob. 25.28SPCh. 25 - Prob. 25.29SPCh. 25 - Prob. 25.30SPCh. 25 - Prob. 25.31SPCh. 25 - Prob. 25.32SP
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