
EBK ORGANIC CHEMISTRY
9th Edition
ISBN: 8220102744097
Author: SIMEK
Publisher: PEARSON
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Chapter 25, Problem 25.25SP
Interpretation Introduction
Interpretation: The pictorial representation of typical Olestra molecule with the use of any fatty acids that are commonly found in vegetable oils is to be stated.
Concept introduction: The sucrose molecule in Olestra has six, seven, or eight fatty acids (most commonly) esterified to its hydroxyl group. The fatty acids come from hydrolysis of vegetable oils such as corn, soybean, coconut, palm and cottonseed oils.
To determine: The pictorial representation of typical Olestra molecule with the use of any fatty acids that are commonly found in vegetable oils.
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Name these organic compounds:
structure
name
CH3
CH3
☐
F
F
CH3
☐
O
Explanation
Check
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Classify each of the following molecules as aromatic, antiaromatic, or nonaromatic.
ZI
NH
Explanation
Check
O aromatic
O antiaromatic
O nonaromatic
O aromatic
O antiaromatic
H
O nonaromatic
O aromatic
O antiaromatic
O nonaromatic
×
Part I.
Draw the stepwise reaction mechanism of each product (a, b, c, d, e, f)
HO
HO
OH
НОН,С
HO
OH
Sucrose
HO
CH₂OH
H
N
N
HO
-H
H
-OH
KMnO4, Heat
H
OH
CH₂OH
(d) Phenyl Osatriazole
OH
НОН,С
HO
HO
+
Glacial HOAC
HO-
HO
CH₂OH
OH
HO
Fructose
(a) Glucose
OH
(b)
H₂N
HN
(c)
CuSO4-5H2O,
ethanol
H
N
N
N
HO
·H
H
OH
H
OH
N
CH₂OH
OH
(f) Phenyl Osazone
H
(e) Carboxy phenyl osatriazole
Figure 2.1. Reaction Scheme for the Total Synthesis of Fine Chemicals
Chapter 25 Solutions
EBK ORGANIC CHEMISTRY
Ch. 25.3 - Prob. 25.1PCh. 25.3A - Prob. 25.2PCh. 25.3B - Give an equaton for the complete transestenfcation...Ch. 25.4 - Prob. 25.4PCh. 25.4 - Several commercial laundry soaps contain...Ch. 25.4 - Prob. 25.6PCh. 25.4 - Prob. 25.7PCh. 25.5 - Prob. 25.8PCh. 25.6 - How would you use a simple extraction to separate...Ch. 25.6 - Prob. 25.10P
Ch. 25.8A - Circle the isoprene units in geranial, menthol,...Ch. 25.8B - Prob. 25.12PCh. 25.8B - Prob. 25.13PCh. 25 - Prob. 25.14SPCh. 25 - Prob. 25.15SPCh. 25 - Show how you would convert oleic acid to the...Ch. 25 - Give the general classification of each compound....Ch. 25 - Phospholipids undergo saponification much like...Ch. 25 - Prob. 25.19SPCh. 25 - Prob. 25.20SPCh. 25 - Prob. 25.21SPCh. 25 - Prob. 25.22SPCh. 25 - Prob. 25.23SPCh. 25 - The structure of limonene appears in Problem25-13....Ch. 25 - Prob. 25.25SPCh. 25 - Prob. 25.26SPCh. 25 - Prob. 25.27SPCh. 25 - Prob. 25.28SPCh. 25 - Prob. 25.29SPCh. 25 - Prob. 25.30SPCh. 25 - Prob. 25.31SPCh. 25 - Prob. 25.32SP
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