The structural formulas, chirality, and the names are to be described for all the constitutionally isomeric ethers in which C 4 H 9 alkyl groups are attached to the oxygen. Concept introduction: The structural formula of a chemical compound consists of a graphic representation of the molecular structure and arrangement of atoms. When isomeric molecules have the same molecular formula, but different bonding patterns and atomic organization, they are known as constitutional isomers. When an oxygen atom is linked to two alkyl or aryl groups having the general formula R-O-R' , it is known as ether. When carbon is attached to four different groups, it is known as the chiral carbon.

Question

Want to see the full answer?

Answer 1

Question

Chapter 25, Problem 78AP

Interpretation Introduction

Interpretation:

The structural formulas, chirality, and the names are to be described for all the constitutionally isomeric ethers in which C4H9 alkyl groups are attached to the oxygen.

Concept introduction:

The structural formula of a chemical compound consists of a graphic representation of the molecular structure and arrangement of atoms.

When isomeric molecules have the same molecular formula, but different bonding patterns and atomic organization, they are known as constitutional isomers.

When an oxygen atom is linked to two alkyl or aryl groups having the general formula R-O-R', it is known as ether.

When carbon is attached to four different groups, it is known as the chiral carbon.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?

One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.