Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 25, Problem 73PP
Interpretation Introduction

Interpretation:

Structure of the tripeptide considered need to be drawn from the given products obtained.

Concept introduction:

Edman degradation is a chemical reaction where the N-terminus amino acid is removed when the peptide is treated with phenyl isothiocyanate followed by treatment with trifluoroacetic acid to form phenylthiohydantoin(PTH) derivative and peptide with one amino acid residue less than the starting peptide.  This method can be used to identify the sequence of the amino acid in peptide as only one amino acid is removed each time forming the PTH derivative.  The general scheme for Edman degradation can be shown as,

Organic Chemistry, Binder Ready Version, Chapter 25, Problem 73PP

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Chapter 25 Solutions

Organic Chemistry, Binder Ready Version

Ch. 25.2 - Prob. 1CCCh. 25.2 - Prob. 2CCCh. 25.2 - Prob. 3CCCh. 25.2 - Prob. 1LTSCh. 25.2 - Prob. 4PTSCh. 25.2 - Prob. 5ATSCh. 25.2 - Prob. 6ATSCh. 25.2 - Prob. 7CCCh. 25.2 - Prob. 8CCCh. 25.2 - Prob. 9CC
Ch. 25.2 - Prob. 10CCCh. 25.3 - Prob. 11CCCh. 25.3 - Prob. 12CCCh. 25.3 - Prob. 13CCCh. 25.3 - Prob. 2LTSCh. 25.3 - Prob. 14PTSCh. 25.3 - Prob. 15ATSCh. 25.3 - Prob. 16ATSCh. 25.3 - Prob. 17CCCh. 25.3 - Prob. 18CCCh. 25.3 - Prob. 19CCCh. 25.3 - Prob. 20CCCh. 25.4 - Prob. 3LTSCh. 25.4 - Prob. 21PTSCh. 25.4 - Prob. 22ATSCh. 25.4 - Prob. 23ATSCh. 25.4 - Prob. 24ATSCh. 25.4 - Prob. 25CCCh. 25.4 - Prob. 26CCCh. 25.4 - Prob. 27CCCh. 25.4 - Prob. 28CCCh. 25.4 - Prob. 29CCCh. 25.5 - Prob. 30CCCh. 25.5 - Prob. 4LTSCh. 25.5 - Prob. 31PTSCh. 25.5 - Prob. 32ATSCh. 25.5 - Prob. 33ATSCh. 25.6 - Prob. 5LTSCh. 25.6 - Prob. 34PTSCh. 25.6 - Prob. 35ATSCh. 25.6 - Prob. 36ATSCh. 25.6 - Prob. 6LTSCh. 25.6 - Prob. 37PTSCh. 25.6 - Prob. 38PTSCh. 25.7 - Prob. 39CCCh. 25 - Prob. 40PPCh. 25 - Prob. 41PPCh. 25 - Prob. 42PPCh. 25 - Prob. 43PPCh. 25 - Prob. 44PPCh. 25 - Prob. 45PPCh. 25 - Prob. 46PPCh. 25 - Prob. 47PPCh. 25 - Prob. 48PPCh. 25 - Prob. 49PPCh. 25 - Prob. 50PPCh. 25 - Prob. 51PPCh. 25 - Prob. 52PPCh. 25 - Prob. 53PPCh. 25 - Prob. 54PPCh. 25 - Prob. 55PPCh. 25 - Prob. 56PPCh. 25 - Prob. 57PPCh. 25 - Prob. 58PPCh. 25 - Prob. 59PPCh. 25 - Prob. 60PPCh. 25 - Prob. 61PPCh. 25 - Prob. 62PPCh. 25 - Prob. 63PPCh. 25 - Prob. 64PPCh. 25 - Prob. 65PPCh. 25 - Prob. 66PPCh. 25 - Prob. 67PPCh. 25 - Prob. 68PPCh. 25 - Prob. 69PPCh. 25 - Prob. 70PPCh. 25 - Prob. 71PPCh. 25 - Prob. 72PPCh. 25 - Prob. 73PPCh. 25 - Prob. 74PPCh. 25 - Prob. 75PPCh. 25 - Prob. 76PPCh. 25 - Prob. 77PPCh. 25 - Prob. 78PPCh. 25 - Prob. 79PPCh. 25 - Prob. 80PPCh. 25 - Prob. 81PPCh. 25 - Prob. 82PPCh. 25 - Prob. 83PPCh. 25 - Prob. 84IPCh. 25 - Prob. 85IPCh. 25 - Prob. 86IPCh. 25 - Prob. 87IP
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