ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 25, Problem 34DSP
Interpretation Introduction

Interpretation:

The number of methylmalonates involved in the biosynthesis of 6-deoxyerythronolide B are to be determined.

Concept introduction:

In the structure of 6-deoxyerythronolide B, methyl malonate is one of the sources of the methyl group.

This methyl group is attached to the alpha carbon atom of the carbonyl C=O or the carbon atom bearing an oxygen functional group -C-O- .

When methyl malonate is used in the biosynthesis of a compound, methyl malonates can be identified as fragments having the CH3-C-C-OH connectivity.

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