Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 25, Problem 33P
A genetic code in which two bases encode a single
amino acid would not be adequate for protein
synthesis. Give a reason why.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 25 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 25.1 - Prob. 25.1QCCh. 25.2 - Problem 26-1 DNA is highly condensed in the...Ch. 25.3 - Prob. 25.3QCCh. 25.4 - Prob. 25.4QCCh. 25.5 - Prob. 25.5QCCh. 25.6 - Prob. 25.6QCCh. 25.7 - Prob. 25.7QCCh. 25.8 - Prob. 25.8QCCh. 25.9 - Prob. 25.9QCCh. 25 - Does the term gene expression refer to: (a)...
Ch. 25 - Prob. 2PCh. 25 - Where does most Of the translation occur in a...Ch. 25 - Prob. 4PCh. 25 - Prob. 5PCh. 25 - Prob. 6PCh. 25 - Prob. 7PCh. 25 - What is the function of RNA polymerase?Ch. 25 - What is the role of helicase in transcription?Ch. 25 - Prob. 10PCh. 25 - Prob. 11PCh. 25 - Prob. 12PCh. 25 - Prob. 13PCh. 25 - Prob. 14PCh. 25 - Prob. 15PCh. 25 - What are the different names used for the two...Ch. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Prob. 20PCh. 25 - Where are the codons located?Ch. 25 - What are the two most important sites on tRNA...Ch. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - (a) If a codon is GCU, what is the anticodon? (b)...Ch. 25 - If a segment of DNA is 981 units long, how many...Ch. 25 - In what sense does the universality of the genetic...Ch. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - A genetic code in which two bases encode a single...Ch. 25 - What is meant by the genetic code being continuous...Ch. 25 - Prob. 35PCh. 25 - Prob. 36PCh. 25 - Prob. 37PCh. 25 - Prob. 38PCh. 25 - Prob. 39PCh. 25 - What are the stages of protein synthesis?Ch. 25 - Prob. 41PCh. 25 - Explain what happens to the fMet initially put at...Ch. 25 - Prob. 43PCh. 25 - Why is amino acid activation called the second...Ch. 25 - Prob. 45PCh. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Prob. 48PCh. 25 - Prob. 49PCh. 25 - What kind of interactions exist between metal-...Ch. 25 - Prob. 51PCh. 25 - Prob. 52PCh. 25 - Prob. 53PCh. 25 - Prob. 54PCh. 25 - Prob. 55PCh. 25 - Prob. 56PCh. 25 - Prob. 57PCh. 25 - Prob. 58PCh. 25 - Prob. 59PCh. 25 - Prob. 60PCh. 25 - Prob. 61PCh. 25 - Prob. 62PCh. 25 - Prob. 63PCh. 25 - Prob. 64PCh. 25 - Prob. 65PCh. 25 - Prob. 66PCh. 25 - Prob. 67PCh. 25 - Prob. 68PCh. 25 - Prob. 69PCh. 25 - Prob. 70PCh. 25 - Prob. 71PCh. 25 - Prob. 72PCh. 25 - Prob. 73PCh. 25 - Prob. 74PCh. 25 - Prob. 75PCh. 25 - Prob. 76PCh. 25 - Prob. 77PCh. 25 - Prob. 78PCh. 25 - Prob. 79PCh. 25 - Prob. 80PCh. 25 - Prob. 81PCh. 25 - Prob. 82PCh. 25 - Prob. 83PCh. 25 - Prob. 84PCh. 25 - Prob. 85PCh. 25 - Prob. 86PCh. 25 - Prob. 87PCh. 25 - Prob. 88PCh. 25 - Prob. 89PCh. 25 - Prob. 90PCh. 25 - Prob. 91PCh. 25 - Prob. 92PCh. 25 - Prob. 93PCh. 25 - Prob. 94PCh. 25 - Prob. 95PCh. 25 - Prob. 96PCh. 25 - Is there any way to prevent a hereditary disease?...Ch. 25 - Prob. 98PCh. 25 - Prob. 99PCh. 25 - Prob. 100PCh. 25 - Glycine, alanine, and valine are classified as...Ch. 25 - Prob. 102PCh. 25 - Which polypeptide is coded for by the mRNA...Ch. 25 - -100 A new endonuclease is found. It cleaves...
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- Zeroth Order Reaction In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI. 2HI(g) Au H2(g) + 12(9) Rate = -d[HI]/dt k = 2.00x104 mol L-1 s-1 If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes? 1 pts Submit Answer Tries 0/5 How long will it take for all of the HI to decompose? 1 pts Submit Answer Tries 0/5 What is the rate of formation of H2 16.0 minutes after the reaction is initiated? 1 pts Submit Answer Tries 0/5arrow_forwardangelarodriguezmunoz149@gmail.com Hi i need help with this question i am not sure what the right answers are.arrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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