Chemistry: Atoms First
3rd Edition
ISBN: 9781259923142
Author: Burdge
Publisher: MCG
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Chapter 25, Problem 25.34QP
Interpretation Introduction
Interpretation: Industrial and laboratory preparation of nitrogen gas has to be given.
Concept introduction:
Industrial preparation – compounds are produced in large scale.
Laboratory preparation – compounds are produced in small scale.
To give: Industrial and laboratory preparation of nitrogen gas
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 25 Solutions
Chemistry: Atoms First
Ch. 25 - Prob. 25.1QPCh. 25 - Prob. 25.2QPCh. 25 - Prob. 25.3QPCh. 25 - Prob. 25.4QPCh. 25 - Prob. 25.5QPCh. 25 - Prob. 25.6QPCh. 25 - Prob. 25.7QPCh. 25 - Prob. 25.8QPCh. 25 - Prob. 25.9QPCh. 25 - Prob. 25.10QP
Ch. 25 - Prob. 25.11QPCh. 25 - Prob. 25.12QPCh. 25 - Elements 17 and 20 form compounds with hydrogen....Ch. 25 - Prob. 25.14QPCh. 25 - Prob. 25.15QPCh. 25 - Prob. 25.16QPCh. 25 - Prob. 25.17QPCh. 25 - Prob. 25.18QPCh. 25 - Prob. 25.19QPCh. 25 - Prob. 25.20QPCh. 25 - Prob. 25.21QPCh. 25 - Prob. 25.22QPCh. 25 - Prob. 25.23QPCh. 25 - Prob. 25.24QPCh. 25 - Prob. 25.25QPCh. 25 - Prob. 25.26QPCh. 25 - Prob. 25.27QPCh. 25 - Prob. 25.28QPCh. 25 - Prob. 25.29QPCh. 25 - Prob. 25.30QPCh. 25 - Prob. 25.31QPCh. 25 - Prob. 25.32QPCh. 25 - Prob. 25.33QPCh. 25 - Prob. 25.34QPCh. 25 - Prob. 25.35QPCh. 25 - Prob. 25.36QPCh. 25 - Prob. 25.37QPCh. 25 - Prob. 25.38QPCh. 25 - Prob. 25.39QPCh. 25 - Prob. 25.40QPCh. 25 - Prob. 25.41QPCh. 25 - At 620 K, the vapor density of ammonium chloride...Ch. 25 - Prob. 25.43QPCh. 25 - Prob. 25.44QPCh. 25 - Prob. 25.45QPCh. 25 - Prob. 25.46QPCh. 25 - Prob. 25.47QPCh. 25 - Prob. 25.48QPCh. 25 - Prob. 25.49QPCh. 25 - Prob. 25.50QPCh. 25 - Prob. 25.51QPCh. 25 - Prob. 25.52QPCh. 25 - Prob. 25.53QPCh. 25 - Prob. 25.54QPCh. 25 - Prob. 25.55QPCh. 25 - Prob. 25.56QPCh. 25 - Prob. 25.57QPCh. 25 - Prob. 25.58QPCh. 25 - Prob. 25.59QPCh. 25 - Prob. 25.60QPCh. 25 - Prob. 25.61QPCh. 25 - Prob. 25.62QPCh. 25 - Prob. 25.63QPCh. 25 - Prob. 25.64QPCh. 25 - Prob. 25.65QPCh. 25 - Prob. 25.66QPCh. 25 - Prob. 25.67QPCh. 25 - Prob. 25.68QPCh. 25 - Prob. 25.69QPCh. 25 - Prob. 25.70QPCh. 25 - Prob. 25.71QPCh. 25 - Prob. 25.72QPCh. 25 - What are the oxidation numbers of O and F in HFO?Ch. 25 - Prob. 25.74QPCh. 25 - Prob. 25.75QPCh. 25 - Prob. 25.76QPCh. 25 - Prob. 25.77QPCh. 25 - Prob. 25.78QPCh. 25 - Prob. 25.79QPCh. 25 - Prob. 25.80QPCh. 25 - Prob. 25.81QPCh. 25 - Prob. 25.82QPCh. 25 - Prob. 25.83QPCh. 25 - Prob. 25.84QPCh. 25 - Iodine pentoxide (I2O5) is sometimes used to...Ch. 25 - Prob. 25.86QPCh. 25 - Prob. 25.87QPCh. 25 - Prob. 25.88QPCh. 25 - Prob. 25.89QPCh. 25 - Prob. 25.90QPCh. 25 - Prob. 25.91QPCh. 25 - Prob. 25.92QPCh. 25 - Prob. 25.93QPCh. 25 - Prob. 25.94QPCh. 25 - Prob. 25.95QPCh. 25 - Prob. 25.96QPCh. 25 - Prob. 25.97QPCh. 25 - Prob. 25.98QPCh. 25 - Prob. 25.99QPCh. 25 - Prob. 25.100QPCh. 25 - Prob. 25.101QPCh. 25 - Prob. 25.102QPCh. 25 - Prob. 25.103QPCh. 25 - Prob. 25.104QP
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