Chemistry: Atoms First
3rd Edition
ISBN: 9781259923142
Author: Burdge
Publisher: MCG
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Chapter 25, Problem 25.20QP
Interpretation Introduction
Interpretation:
The usage of cyanide ions in metallurgy has to be explained.
Concept introduction:
Metallurgy
It is a process of separation of metals from their ores and changing its properties for particular use.
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 25 Solutions
Chemistry: Atoms First
Ch. 25 - Prob. 25.1QPCh. 25 - Prob. 25.2QPCh. 25 - Prob. 25.3QPCh. 25 - Prob. 25.4QPCh. 25 - Prob. 25.5QPCh. 25 - Prob. 25.6QPCh. 25 - Prob. 25.7QPCh. 25 - Prob. 25.8QPCh. 25 - Prob. 25.9QPCh. 25 - Prob. 25.10QP
Ch. 25 - Prob. 25.11QPCh. 25 - Prob. 25.12QPCh. 25 - Elements 17 and 20 form compounds with hydrogen....Ch. 25 - Prob. 25.14QPCh. 25 - Prob. 25.15QPCh. 25 - Prob. 25.16QPCh. 25 - Prob. 25.17QPCh. 25 - Prob. 25.18QPCh. 25 - Prob. 25.19QPCh. 25 - Prob. 25.20QPCh. 25 - Prob. 25.21QPCh. 25 - Prob. 25.22QPCh. 25 - Prob. 25.23QPCh. 25 - Prob. 25.24QPCh. 25 - Prob. 25.25QPCh. 25 - Prob. 25.26QPCh. 25 - Prob. 25.27QPCh. 25 - Prob. 25.28QPCh. 25 - Prob. 25.29QPCh. 25 - Prob. 25.30QPCh. 25 - Prob. 25.31QPCh. 25 - Prob. 25.32QPCh. 25 - Prob. 25.33QPCh. 25 - Prob. 25.34QPCh. 25 - Prob. 25.35QPCh. 25 - Prob. 25.36QPCh. 25 - Prob. 25.37QPCh. 25 - Prob. 25.38QPCh. 25 - Prob. 25.39QPCh. 25 - Prob. 25.40QPCh. 25 - Prob. 25.41QPCh. 25 - At 620 K, the vapor density of ammonium chloride...Ch. 25 - Prob. 25.43QPCh. 25 - Prob. 25.44QPCh. 25 - Prob. 25.45QPCh. 25 - Prob. 25.46QPCh. 25 - Prob. 25.47QPCh. 25 - Prob. 25.48QPCh. 25 - Prob. 25.49QPCh. 25 - Prob. 25.50QPCh. 25 - Prob. 25.51QPCh. 25 - Prob. 25.52QPCh. 25 - Prob. 25.53QPCh. 25 - Prob. 25.54QPCh. 25 - Prob. 25.55QPCh. 25 - Prob. 25.56QPCh. 25 - Prob. 25.57QPCh. 25 - Prob. 25.58QPCh. 25 - Prob. 25.59QPCh. 25 - Prob. 25.60QPCh. 25 - Prob. 25.61QPCh. 25 - Prob. 25.62QPCh. 25 - Prob. 25.63QPCh. 25 - Prob. 25.64QPCh. 25 - Prob. 25.65QPCh. 25 - Prob. 25.66QPCh. 25 - Prob. 25.67QPCh. 25 - Prob. 25.68QPCh. 25 - Prob. 25.69QPCh. 25 - Prob. 25.70QPCh. 25 - Prob. 25.71QPCh. 25 - Prob. 25.72QPCh. 25 - What are the oxidation numbers of O and F in HFO?Ch. 25 - Prob. 25.74QPCh. 25 - Prob. 25.75QPCh. 25 - Prob. 25.76QPCh. 25 - Prob. 25.77QPCh. 25 - Prob. 25.78QPCh. 25 - Prob. 25.79QPCh. 25 - Prob. 25.80QPCh. 25 - Prob. 25.81QPCh. 25 - Prob. 25.82QPCh. 25 - Prob. 25.83QPCh. 25 - Prob. 25.84QPCh. 25 - Iodine pentoxide (I2O5) is sometimes used to...Ch. 25 - Prob. 25.86QPCh. 25 - Prob. 25.87QPCh. 25 - Prob. 25.88QPCh. 25 - Prob. 25.89QPCh. 25 - Prob. 25.90QPCh. 25 - Prob. 25.91QPCh. 25 - Prob. 25.92QPCh. 25 - Prob. 25.93QPCh. 25 - Prob. 25.94QPCh. 25 - Prob. 25.95QPCh. 25 - Prob. 25.96QPCh. 25 - Prob. 25.97QPCh. 25 - Prob. 25.98QPCh. 25 - Prob. 25.99QPCh. 25 - Prob. 25.100QPCh. 25 - Prob. 25.101QPCh. 25 - Prob. 25.102QPCh. 25 - Prob. 25.103QPCh. 25 - Prob. 25.104QP
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