The phenomenon of mutarotation with reference to carbohydrates has to be explained. The detection of mutarotation has to be explained. Concept Introduction: When carbohydrates are dissolved in water, the specific rotation of the anomeric forms are interconverted (α-form to β-form) and attains equilibrium. This interconversion of the anomers is said to be mutarotation.

Question

Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Answer 1

Question

Chapter 25, Problem 25.22P

Interpretation Introduction

Interpretation:

The phenomenon of mutarotation with reference to carbohydrates has to be explained. The detection of mutarotation has to be explained.

Concept Introduction:

When carbohydrates are dissolved in water, the specific rotation of the anomeric forms are interconverted (α-form to β-form) and attains equilibrium. This interconversion of the anomers is said to be mutarotation.

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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

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