ORGANIC CHEMISTRY-OWL V2 ACCESS
ORGANIC CHEMISTRY-OWL V2 ACCESS
8th Edition
ISBN: 9781305582422
Author: Brown
Publisher: CENGAGE L
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Chapter 25, Problem 25.20P

(a)

Interpretation Introduction

Interpretation:

The given Haworth projection structure has to be converted into an open chain form and to Fischer projection and the name of the monosaccharide has to be given.

Concept Introduction:

In Haworth projection, the aldehyde or ketonic carbon is fused with –OH of penultimate carbon to form pyranose or furanose cyclic structures.  In open chain form, the ring is opened.  In Fischer projection, the structure is represented in two dimensional form.

(b)

Interpretation Introduction

Interpretation:

The given Haworth projection structure has to be converted into an open chain form and to Fischer projection and the name of the monosaccharide has to be given.

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f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? H₂C H₂C CH2 1.60Å ハ C. * CH₂ H₂C * C H₂ 120°
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