
(a)
Interpretation:
The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium
(b)
Interpretation:
The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium
(c)
Interpretation:
The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium

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Chapter 24 Solutions
Chemistry: Atoms First
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- For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward
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