Chemistry: Atoms First
Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
Question
Book Icon
Chapter 24.6, Problem 4PPA

(a)

Interpretation Introduction

Interpretation:

The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.

Concept Introduction:

Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.

Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.

  • n- type semiconductor:  (conduction is due to movement of extra electrons)

The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.

Example: Silicon (natural semiconductor) and Phosphorus

  • p-type semiconductor: (conduction is due to movement of holes)

The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.

Example: Silicon (natural semiconductor) and Gallium

(b)

Interpretation Introduction

Interpretation:

The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.

Concept Introduction:

Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.

Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.

  • n- type semiconductor:  (conduction is due to movement of extra electrons)

The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.

Example: Silicon (natural semiconductor) and Phosphorus

  • p-type semiconductor: (conduction is due to movement of holes)

The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.

Example: Silicon (natural semiconductor) and Gallium

(c)

Interpretation Introduction

Interpretation:

The elements needed to combine with the given set of elements in order to form good semiconductor should be determined.

Concept Introduction:

Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.

Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.

  • n- type semiconductor:  (conduction is due to movement of extra electrons)

The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increases the conductivity.

Example: Silicon (natural semiconductor) and Phosphorus

  • p-type semiconductor: (conduction is due to movement of holes)

The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.

Example: Silicon (natural semiconductor) and Gallium

Blurred answer
Students have asked these similar questions
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density × NO2 ○ donating O donating O withdrawing O withdrawing O electron-rich electron-deficient no inductive effects O no resonance effects O similar to benzene E [ CI O donating withdrawing O no inductive effects Explanation Check ○ donating withdrawing no resonance effects electron-rich electron-deficient O similar to benzene © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Acces
Understanding how substituents activate Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation HN NH2 Check X (Choose one) (Choose one) (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center A
Identifying electron-donating and electron-withdrawing effects on benzene For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Inductive Effects Resonance Effects Overall Electron-Density Molecule CF3 O donating O donating O withdrawing O withdrawing O no inductive effects O no resonance effects electron-rich electron-deficient O similar to benzene CH3 O donating O withdrawing O no inductive effects O donating O withdrawing Ono resonance effects O electron-rich O electron-deficient O similar to benzene Explanation Check Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center

Chapter 24 Solutions

Chemistry: Atoms First

Ch. 24.3 - Would the following molecule make a good liquid...Ch. 24.3 - Prob. 3PPACh. 24.3 - Prob. 3PPBCh. 24.3 - Prob. 3PPCCh. 24.3 - Prob. 24.3.1SRCh. 24.3 - Prob. 24.3.2SRCh. 24.6 - Prob. 24.4WECh. 24.6 - Prob. 4PPACh. 24.6 - Prob. 4PPBCh. 24.6 - Prob. 4PPCCh. 24.6 - Prob. 24.6.1SRCh. 24 - Bakelite, the first commercially produced polymer,...Ch. 24 - Prob. 24.2QPCh. 24 - Prob. 24.3QPCh. 24 - Prob. 24.4QPCh. 24 - Prob. 24.5QPCh. 24 - Prob. 24.6QPCh. 24 - Prob. 24.7QPCh. 24 - Describe two natural types of composite materials...Ch. 24 - Prob. 24.9QPCh. 24 - Amorphous silica (SiO2) can be formed in uniform...Ch. 24 - Prob. 24.11QPCh. 24 - Prob. 24.12QPCh. 24 - Prob. 24.13QPCh. 24 - Prob. 24.14QPCh. 24 - Prob. 24.15QPCh. 24 - Prob. 24.16QPCh. 24 - Prob. 24.17QPCh. 24 - Prob. 24.18QPCh. 24 - Prob. 24.19QPCh. 24 - Prob. 24.20QPCh. 24 - Prob. 24.21QPCh. 24 - How does an STM measure the peak and valley...Ch. 24 - Prob. 24.23QPCh. 24 - Prob. 24.24QPCh. 24 - Prob. 24.25QPCh. 24 - Prob. 24.26QPCh. 24 - Prob. 24.27QPCh. 24 - Prob. 24.28QPCh. 24 - Prob. 24.29QPCh. 24 - Prob. 24.30QPCh. 24 - Prob. 24.31QPCh. 24 - Prob. 24.32QPCh. 24 - Prob. 24.33QPCh. 24 - Prob. 24.34QPCh. 24 - Prob. 24.35QPCh. 24 - Prob. 24.36QPCh. 24 - Prob. 24.37QPCh. 24 - Draw representations of block copolymers and graft...Ch. 24 - Prob. 24.39QPCh. 24 - Prob. 24.40QPCh. 24 - Prob. 24.41QPCh. 24 - Prob. 24.42QPCh. 24 - Prob. 24.43QPCh. 24 - Prob. 24.44QPCh. 24 - Prob. 24.45QPCh. 24 - Prob. 24.46QPCh. 24 - Prob. 24.47QPCh. 24 - Prob. 24.48QP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Text book image
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning