
(a)
Interpretation:
The given set of combinations should be identified that whether they form good semiconductor.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increase the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium
To Determine: The given combination of elements will form semiconductor or not.
(b)
Interpretation:
The given set of combinations should be identified that whether they form good semiconductor.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increase the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium
To Determine: The given combination of elements will form semiconductor or not.
(c)
Interpretation:
The given set of combinations should be identified that whether they form good semiconductor.
Concept Introduction:
Semiconductors are substances that conduct electricity either by addition of an impurity or by the effects of temperature on it. Semiconductors have small energy gap between valence and conduction band hence its electrical conductivity lies between conductor and insulator.
Addition of impurity to a semiconductor is termed as doping. Doping alters the conductivity of a semiconductor. The addition of an element having either more or less number of valence electrons than the natural semiconductor decides the combination as the following two types of semiconductor.
- n- type semiconductor: (conduction is due to movement of extra electrons)
The element added will have more valence electron than the natural semiconductor. Therefore, the extra electron from the added element resides in conduction band and increase the conductivity.
Example: Silicon (natural semiconductor) and Phosphorus
- p-type semiconductor: (conduction is due to movement of holes)
The element added will have less valence electron than the natural semiconductor. Here, instead of extra electron, there will be “holes” at the places, where a semiconductor is replaced by added element. A p-type semiconductor increases conductivity because the holes (effective positive charge; lies at valence band) move through the natural semiconductor rather than electrons.
Example: Silicon (natural semiconductor) and Gallium
To Determine: The given combination of elements will form semiconductor or not.

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Chapter 24 Solutions
Chemistry: Atoms First
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- Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and the follow the arrows to draw the intermediate and product in this reaction or mechanistic step(s).arrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the intermediates and product of the following reaction or mechanistic step(s).arrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the arrows to draw the intermediate and the product in this reaction or mechanistic step(s).arrow_forward
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