a) p -Nitroaniline, p -aminobenzaldehyde, p -bromoaniline Interpretation: The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity. Concept introduction: Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 3

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 4

Question

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

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Answer 5

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 6

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 7

Chapter 24.4, Problem 6P

Interpretation Introduction

a) p-Nitroaniline, p-aminobenzaldehyde, p-bromoaniline

Interpretation:

The compounds p-nitroaniline, p-aminobenzaldehyde and p-bromoaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 8

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 9

Interpretation Introduction

b) p-Chloroaniline, p-aminoacetophenone, p-methylaniline

Interpretation:

The compounds p-chloroaniline, p-aminoacetophenone and p-methylaniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 10

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 11

Interpretation Introduction

c) p-(trifluoromethyl)aniline, p-methylaniline, p-(fluoromethyl)aniline

Interpretation:

The compounds p-(trifluoromethyl)aniline, p-methylaniline and p-(fluoromethyl) aniline are to be arranged in the increasing order of their basicity.

Concept introduction:

Amines are basic as they can donate the lone pair if electrons on the N atom. Generally aryl amines are less basic than alkyl amines. An electron withdrawing substituent present on the aromatic ring reduces the base strength while an electron releasing substituent present on the aromatic ring enhances the base strength.

Answer 12

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Answer 23

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

Chapter 24 Solutions