a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Question

Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer d, e, and f

If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

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Answer 5

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 6

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 7

Chapter 24.6, Problem 11P

Interpretation Introduction

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 8

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Answer 9

Interpretation Introduction

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

Answer 10

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 11

Interpretation Introduction

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Answer 12

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Answer 13

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Answer 23

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Solution Summary: The author explains how a retrosynthetic strategy looks at the target molecule and works backwards to arrive at starting materials.

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

Chapter 24 Solutions

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Solution Summary: The author explains how a retrosynthetic strategy looks at the target molecule and works backwards to arrive at starting materials.

a) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

b) Interpretation: To describe how the amines to be prepared using reductive amination reactions

c) Interpretation: To describe how the amines to be prepared using reductive amination reactions.

Chapter 24 Solutions

a)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.

b)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions

c)

Interpretation:

To describe how the amines to be prepared using reductive amination reactions.