(a)
Interpretation:
For the two stereo isomeric ketotetroses, the structure, stereo isomeric relationship and stereo disrupters are needed to be determined.
Concept introduction:
- Ketoses are monosaccharides, which contains
ketone group. - The naming of monosaccharides,
- Prefix: aldo or keto indicates whether the monosaccharide is containing
aldehyde or ketone group. - Suffix: ose indicates the carbohydrates
- Root word: indicate the number of carbons.
- Prefix: aldo or keto indicates whether the monosaccharide is containing
- The stereo-descriptor used for monosaccharides is D or L. it is based on the dextrorotatory glyceraldehyde or levorotatory glyceraldehyde.
- Enantiomers are non-super imposable mirror images of each other.
To determine: the structure of two stereo isomeric ketotetroses.
(b)
Interpretation:
For the two stereo isomeric ketotetroses, the structure, stereo isomeric relationship and stereo disrupters are needed to be determined.
Concept introduction:
- Ketoses are monosaccharides, which contains ketone group.
- The naming of monosaccharides,
- Prefix: aldo or keto indicates whether the monosaccharide is containing aldehyde or ketone group.
- Suffix: ose indicates the carbohydrates
- Root word: indicate the number of carbons.
- The stereo-descriptor used for monosaccharides is D or L. it is based on the dextrorotatory glyceraldehyde or levorotatory glyceraldehyde.
- Enantiomers are non-super imposable mirror images of each other.
To identify: the stereo isomeric relationship.
(c)
Interpretation:
For the two stereo isomeric ketotetroses, the structure, stereo isomeric relationship and stereo disrupters are needed to be determined.
Concept introduction:
- Ketoses are monosaccharides, which contains ketone group.
- The naming of monosaccharides,
- Prefix: aldo or keto indicates whether the monosaccharide is containing aldehyde or ketone group.
- Suffix: ose indicates the carbohydrates
- Root word: indicate the number of carbons.
- The stereo-descriptor used for monosaccharides is D or L. it is based on the dextrorotatory glyceraldehyde or levorotatory glyceraldehyde.
- Enantiomers are non-super imposable mirror images of each other.
To identify: the D sugar and L sugar from the two structures of stereo isomeric ketotetroses.
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Chapter 24 Solutions
ORG.CHEM.WILEYPLUSNEXTGEN.W/LLTEXT+STDY.
- Check all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forward
- For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forwardCheck the box if the molecule contains the listed item. *See imagearrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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