ORG.CHEM.WILEYPLUSNEXTGEN.W/LLTEXT+STDY.
4th Edition
ISBN: 9781119832638
Author: Klein
Publisher: WILEY
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Question
Chapter 24.2, Problem 4CC
(a)
Interpretation Introduction
Interpretation:
The Fischer projection of D-Allose and L-Allose are needed to be determined if the four chirality centers of D-Allose are in R-configuration.
Concept introduction:
- Fischer projection of carbohydrates are drawn by vertical line representing the cyclic carbon chain and the attached OH and H groups are placed in right or left side of each carbon atoms. The position of carbonyl group is on top of the line.
- R and S configuration of chiral carbons of carbohydrates are depending upon the location of –OH groups on the each carbon atom in Fischer projection.
- If the –OH group is in right side then, the configuration is R.
- If the –OH group is in left side then, the configuration is S.
- D and L configuration of a sugar are Enantiomers.
- Enantiomers are non-super imposable mirror images of each other.
To draw: the Fischer projection of D-Allose, if the four chirality centers of D-Allose are in R-configuration.
(b)
Interpretation Introduction
Interpretation:
The Fischer projection of D-Allose and L-Allose are needed to be determined if the four chirality centers of D-Allose are in R-configuration.
Concept introduction:
- Fischer projection of carbohydrates are drawn by vertical line representing the cyclic carbon chain and the attached OH and H groups are placed in right or left side of each carbon atoms. The position of carbonyl group is on top of the line.
- R and S configuration of chiral carbons of carbohydrates are depending upon the location of –OH groups on the each carbon atom in Fischer projection.
- If the –OH group is in right side then, the configuration is R.
- If the –OH group is in left side then, the configuration is S.
- D and L configuration of a sugar are Enantiomers.
- Enantiomers are non-super imposable mirror images of each other.
To draw: the Fischer projection of L-Allose.
Expert Solution & Answer
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Chapter 24 Solutions
ORG.CHEM.WILEYPLUSNEXTGEN.W/LLTEXT+STDY.
Ch. 24.2 - Prob. 1CCCh. 24.2 - Prob. 2CCCh. 24.2 - Prob. 3CCCh. 24.2 - Prob. 4CCCh. 24.2 - Prob. 5CCCh. 24.2 - Prob. 6CCCh. 24.4 - Prob. 7CCCh. 24.4 - Prob. 8CCCh. 24.5 - Prob. 1LTSCh. 24.5 - Prob. 9PTS
Ch. 24.5 - Prob. 2LTSCh. 24.5 - Prob. 12PTSCh. 24.5 - Prob. 13PTSCh. 24.5 - Prob. 3LTSCh. 24.5 - Prob. 16PTSCh. 24.5 - Prob. 19CCCh. 24.5 - Prob. 20CCCh. 24.5 - Prob. 21CCCh. 24.5 - Prob. 22CCCh. 24.6 - Prob. 23CCCh. 24.6 - Prob. 24CCCh. 24.6 - Prob. 25CCCh. 24.6 - Prob. 26CCCh. 24.6 - Prob. 27CCCh. 24.6 - Prob. 28CCCh. 24.6 - Prob. 29CCCh. 24.6 - Prob. 30CCCh. 24.6 - Prob. 4LTSCh. 24.6 - Prob. 31PTSCh. 24.6 - Prob. 34CCCh. 24.6 - Prob. 35CCCh. 24.6 - Prob. 36CCCh. 24.6 - Prob. 37CCCh. 24.6 - Prob. 38CCCh. 24.7 - Prob. 5LTSCh. 24.7 - Prob. 39PTSCh. 24.7 - Prob. 41CCCh. 24 - Prob. 42PPCh. 24 - Prob. 43PPCh. 24 - Prob. 44PPCh. 24 - Prob. 45PPCh. 24 - Prob. 46PPCh. 24 - Prob. 47PPCh. 24 - Prob. 48PPCh. 24 - Prob. 49PPCh. 24 - Prob. 50PPCh. 24 - Prob. 51PPCh. 24 - Prob. 52PPCh. 24 - Prob. 53PPCh. 24 - Prob. 54PPCh. 24 - Prob. 55PPCh. 24 - Prob. 56PPCh. 24 - Prob. 57PPCh. 24 - Prob. 58PPCh. 24 - Prob. 59PPCh. 24 - Prob. 60PPCh. 24 - Prob. 61PPCh. 24 - Prob. 62PPCh. 24 - Prob. 63PPCh. 24 - Prob. 64PPCh. 24 - Prob. 65PPCh. 24 - Prob. 66PPCh. 24 - Prob. 67PPCh. 24 - Prob. 68PPCh. 24 - Prob. 69PPCh. 24 - Prob. 70PPCh. 24 - Prob. 71PPCh. 24 - Prob. 72PPCh. 24 - Prob. 73PPCh. 24 - Prob. 74PPCh. 24 - Prob. 75PPCh. 24 - Prob. 76PPCh. 24 - Prob. 77PPCh. 24 - Prob. 78PPCh. 24 - Prob. 79PPCh. 24 - Prob. 80PPCh. 24 - Prob. 86IPCh. 24 - Prob. 87IPCh. 24 - Prob. 88IPCh. 24 - Prob. 89IP
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