Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 24, Problem 51E
(a)
Interpretation Introduction
To determine: The acid and base among the reactants in the given reaction and state whether the acid and base in the given reaction is Bronsted-Lowry acid and base, Lewis acid and base or
(b)
Interpretation Introduction
To determine: The acid and base among the reactants in the given reaction and state whether the acid and base in the given reaction is Bronsted-Lowry acid and base, Lewis acid and base or Arrhenius acid and base.
(c)
Interpretation Introduction
To determine: The acid and base among the reactants in the given reaction and state whether the acid and base in the given reaction is Bronsted-Lowry acid and base, Lewis acid and base or Arrhenius acid and base.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 24 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 24.2 - Prob. 24.2.1PECh. 24.2 - Le Chatelier noted that many industrial processes...Ch. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 24.3 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - The following equilibria were measured at 823 K:...Ch. 24.7 - Prob. 24.7.1PECh. 24.7 - Prob. 24.7.2PECh. 24.7 - At 800 K, the equilibrium constant for the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Practice Exercise 2 Predict whether the...Ch. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Practice Exercise 2 For each reaction, use Figure...Ch. 24 - Practice Exercise 1 In a certain acidic solution...Ch. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 24 - Practice Exercise 2 In a sample of lemon juice,...Ch. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 24 - Prob. 25ECh. 24 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 24 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 24 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 24 - Prob. 29ECh. 24 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 24 - Prob. 31ECh. 24 - Practice Exercise 2 Which of the following...Ch. 24 - Prob. 33ECh. 24 - Practice Exercise 2 What is the morality of an...Ch. 24 - Practice Exercise 1 By using information from...Ch. 24 - Practice Exercise 2 Based on information in...Ch. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Practice Exercise 1 How many of the following...Ch. 24 - In each pair, choose the compound that gives the...Ch. 24 - Prob. 41ECh. 24 - a. Identify the Br ted-Lowry acid and base in the...Ch. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - 16.5 The following diagrams represent aqueous...Ch. 24 - Prob. 47ECh. 24 - Which of these statements about how the percent...Ch. 24 - 16.8 Each of the three molecules shown here...Ch. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - 16.14 Which of the following statements is...Ch. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Identify the Bronsted-Lowry acid and the...Ch. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - 16.29 Calcualte [H +] for each of the following...Ch. 24 - Prob. 67ECh. 24 - 16.31 At the freezing point of water (0 o C), K10...Ch. 24 - Prob. 69ECh. 24 - 16.35 Complete the following table by calculating...Ch. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - write the chemical equation and the Ka expression...Ch. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Calculate the percent ionization of hydrazoic acid...Ch. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 24 - Prob. 100IECh. 24 - Practice Exercise 1 Consider the following...Ch. 24 - Prob. 102IE
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