Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 24, Problem 11E
Interpretation Introduction
Interpretation:
Ammonia being an organic molecule is to be validated.
Concept introduction: Organic compounds form the basis of chemistry. Carbon atom is the primary requirement of a compound to be organic.
To determine: If ammonia is an organic molecule with explanation.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 24 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 24.2 - Prob. 24.1.1PECh. 24.2 - The equilibrium constant Kc for C(s) +CO2 2CO(g)...Ch. 24.2 - Prob. 24.2.1PECh. 24.2 - Le Chatelier noted that many industrial processes...Ch. 24.3 - Prob. 24.3.1PECh. 24.3 - Prob. 24.3.2PECh. 24.3 - [15.91] An equilibrium mixture of H2, I2, and HI...Ch. 24.3 - Consider the hypothetical reaction A(g) + 2B(g) 2...Ch. 24.3 - Prob. 24.5.1PECh. 24.3 - Prob. 24.5.2PE
Ch. 24.4 - Prob. 24.6.1PECh. 24.4 - The following equilibria were measured at 823 K:...Ch. 24.7 - Prob. 24.7.1PECh. 24.7 - Prob. 24.7.2PECh. 24.7 - At 800 K, the equilibrium constant for the...Ch. 24.7 - Prob. 24.8.2PECh. 24 - Practice Exercise 1 A solution at 25° C has pOH =...Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Practice Exercise 2 Predict whether the...Ch. 24 - Prob. 4ECh. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10ECh. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - Practice Exercise 2 For each reaction, use Figure...Ch. 24 - Practice Exercise 1 In a certain acidic solution...Ch. 24 - Prob. 15ECh. 24 - Prob. 16ECh. 24 - Prob. 17ECh. 24 - Practice Exercise 1 A solution at 250C has [OH-] =...Ch. 24 - Practice Exercise 2 In a sample of lemon juice,...Ch. 24 - Prob. 20ECh. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Practice Exercise 2 Niacin, one of the B vitamins,...Ch. 24 - Prob. 25ECh. 24 - Practice Exercise 2 A 0.020 M solution of niacin...Ch. 24 - Practice Exercise 1 What is the pH of a 0.40 M...Ch. 24 - Practice Exercise 2 The Ka for niacin (Sample...Ch. 24 - Prob. 29ECh. 24 - Practice Exercise 2 Calculate the pH of a 0.020 M...Ch. 24 - Prob. 31ECh. 24 - Practice Exercise 2 Which of the following...Ch. 24 - Prob. 33ECh. 24 - Practice Exercise 2 What is the morality of an...Ch. 24 - Practice Exercise 1 By using information from...Ch. 24 - Practice Exercise 2 Based on information in...Ch. 24 - Prob. 37ECh. 24 - Prob. 38ECh. 24 - Practice Exercise 1 How many of the following...Ch. 24 - In each pair, choose the compound that gives the...Ch. 24 - Prob. 41ECh. 24 - a. Identify the Br ted-Lowry acid and base in the...Ch. 24 - Prob. 43ECh. 24 - Prob. 44ECh. 24 - Prob. 45ECh. 24 - 16.5 The following diagrams represent aqueous...Ch. 24 - Prob. 47ECh. 24 - Which of these statements about how the percent...Ch. 24 - 16.8 Each of the three molecules shown here...Ch. 24 - Prob. 50ECh. 24 - Prob. 51ECh. 24 - Prob. 52ECh. 24 - 16.14 Which of the following statements is...Ch. 24 - Prob. 54ECh. 24 - Prob. 55ECh. 24 - Identify the Bronsted-Lowry acid and the...Ch. 24 - Prob. 57ECh. 24 - Prob. 58ECh. 24 - Prob. 59ECh. 24 - Prob. 60ECh. 24 - Prob. 61ECh. 24 - Prob. 62ECh. 24 - Prob. 63ECh. 24 - Prob. 64ECh. 24 - Prob. 65ECh. 24 - 16.29 Calcualte [H +] for each of the following...Ch. 24 - Prob. 67ECh. 24 - 16.31 At the freezing point of water (0 o C), K10...Ch. 24 - Prob. 69ECh. 24 - 16.35 Complete the following table by calculating...Ch. 24 - Prob. 71ECh. 24 - Prob. 72ECh. 24 - 16.38 Carbon dioxide in the atmosphere dissolves...Ch. 24 - Prob. 74ECh. 24 - Prob. 75ECh. 24 - Prob. 76ECh. 24 - Prob. 77ECh. 24 - Prob. 78ECh. 24 - Prob. 79ECh. 24 - Prob. 80ECh. 24 - Prob. 81AECh. 24 - Prob. 82AECh. 24 - write the chemical equation and the Ka expression...Ch. 24 - Prob. 84AECh. 24 - Prob. 85AECh. 24 - Prob. 86AECh. 24 - Prob. 87AECh. 24 - Prob. 88AECh. 24 - Prob. 89AECh. 24 - Prob. 90AECh. 24 - Prob. 91AECh. 24 - Prob. 92AECh. 24 - Prob. 93AECh. 24 - Calculate the percent ionization of hydrazoic acid...Ch. 24 - Prob. 95IECh. 24 - Prob. 96IECh. 24 - Prob. 97IECh. 24 - Prob. 98IECh. 24 - 16.68 The hypochlorite ion, CIO- , acts as a weak...Ch. 24 - Prob. 100IECh. 24 - Practice Exercise 1 Consider the following...Ch. 24 - Prob. 102IE
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