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Chapter 24, Problem 36P

The glycine cleavage system is a group of four enzymes that together catalyze the following reaction:

glycine + THF glycine cleavage system N 5 , N 10 methylene THF + CO 2

Use the following information to determine the sequence of reactions carried out by the glycine cleavage system:

a. The first enzyme is a PLP-requiring decarboxylase.

b. The second enzyme is aminomethyltransferase. This enzyme has a lipoate coenzyme.

c. The third enzyme synthesizes N5,N10-methylene-THF and also forms +NH4.

d. The fourth enzyme is an FAD-requiring enzyme.

e. The cleavage system also requires NAD+.

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Chapter 24 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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