Formation of product of amino acid when α -keto group accepts the amino group from pyrodoxamine has to be determined. Concept introduction: In an enzyme – catalysed reaction that requires coenzymes B 12 , a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

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Answer 1

Question

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

AE>AE₁ (Y/N) AE=AE₁ (Y/N) AE

Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br A

Answer 2

Question

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

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Answer 3

Question

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

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Answer 4

Question

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

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Answer 5

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Answer 6

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Answer 7

Chapter 24.5, Problem 12P

(a)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes B12, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Formation of product of amino acid when α-keto group accepts the amino group from pyrodoxamine has to be determined.

Concept introduction:

In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.2 - How many conjugated double bonds are there in a....Ch. 24.2 - Instead of adding to the 4a position and...Ch. 24.2 - Prob. 7P Ch. 24.3 - Prob. 8P Ch. 24.3 - Acetolactate synthase is another TPP-requiring...Ch. 24.3 - Acetolactate synthase transfers the acyl group of...Ch. 24.5 - Prob. 12P Ch. 24.5 - The enzyme that catalyzes the C C bond cleavage...

Formation of product of amino acid when α -keto group accepts the amino group from pyrodoxamine has to be determined. Concept introduction: In an enzyme – catalysed reaction that requires coenzymes B 12 , a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.

Solution Summary: The author explains the formation of product of amino acid when alpha -keto group accepts the amino group from pyrodoxamine has to be determined.

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