Chirality and the alcohol based structural isomer should be identified for the given formula of C 6 H 14 O Concept introduction: Isomer: Molecule has same molecular formula but different structural arrangement is called isomer. Chiral: Absence of a plane of symmetry or a center of symmetry is called chiral molecule, a non-superimposable on its mirror image is called chiral. A carbon atom is attached by the four different groups is called chiral carbon. Achiral: Presence of a plane of symmetry or a center of symmetry is called achiral molecule, a superimposable on its mirror image is called achiral. A carbon atom does not have four different groups is called achiral carbon

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Chapter 24, Problem 24.73QP

Interpretation Introduction

Interpretation:

Chirality and the alcohol based structural isomer should be identified for the given formula of C6H14O

Concept introduction:

Isomer: Molecule has same molecular formula but different structural arrangement is called isomer.

Chiral: Absence of a plane of symmetry or a center of symmetry is called chiral molecule, a non-superimposable on its mirror image is called chiral. A carbon atom is attached by the four different groups is called chiral carbon.

Achiral: Presence of a plane of symmetry or a center of symmetry is called achiral molecule, a superimposable on its mirror image is called achiral. A carbon atom does not have four different groups is called achiral carbon

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• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

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