The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained. Concept introduction: A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis . The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

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Answer 1

Question

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

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Answer 2

Question

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

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Answer 3

Question

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

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Answer 4

Question

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

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Answer 5

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

Answer 6

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

Answer 7

Chapter 24, Problem 24.69P

Interpretation Introduction

Interpretation:

The structure of the product of given reaction is to be drawn and the formation of benzyne intermediate is to be explained.

Concept introduction:

A nucleophilic aromatic substitution reaction is a substitution reaction in which the nucleophile displaces a good leaving group such as halide on the aromatic ring. Generally, proton transfer is the first step for the formation of nucleophile. Diels-Alder is one of the important reactions in organic synthesis. The Diels –Alder reaction involves diene and dienophile. Adiene contribute four Pi-electrons from a pair of conjugated pi-bond. And dienophile contributes two electrons from single pi-bond.

Answer 8

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Answer 11

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Prob. 24.3P Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

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Chapter 24 Solutions