(a) Interpretation: The relationship between glucose and mannose is to be stated as they both give same osazone. Concept Introduction: Aldose are the carbohydrates which contains aldehyde as functional group . Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C − 1 and C − 2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

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Answer 1

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Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+

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Answer 2

Question

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

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Answer 3

Question

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

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Answer 4

Question

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

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Answer 5

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Answer 6

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Answer 7

Chapter 24, Problem 24.44AP

Interpretation Introduction

(a)

Interpretation:

The relationship between glucose and mannose is to be stated as they both give same osazone.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The aldopentose that gives the same osazone as D− arabinose is to be stated.

Concept Introduction:

Aldose are the carbohydrates which contains aldehyde as functional group. Osazone are formed when carbohydrates reacts with excess of phenylhydrazine. In osazone formation the stereochemistry of C−1 and C−2 carbons is lost. Epimers are those compounds which differ in configuration at only one carbon.

Answer 10

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Answer 12

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Answer 13

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Prob. 24.3P Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains the relationship between glucose and mannose as they both give the same osazone.

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Chapter 24 Solutions