EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
6th Edition
ISBN: 9781319385415
Author: PARISE
Publisher: VST
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Chapter 24, Problem 24.29P
Interpretation Introduction

Interpretation:

The structure of two aldoses obtained from the given illustration is to be assigned.

Concept Introduction:

In Ruff degradation reaction, aldose is oxidized to aldonic acid. Calcium salts of aldonic acid react with ferric ion and hydrogen peroxide to give decarboxylated calcium salts of aldonic acid. The C2 carbon of aldose oxidizes to aldehyde group.

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Show how you would accomplish the following transformations. More than one step may be required. ow all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3CH2C-CN CH3 CH3.
Show how you would accomplish the following transformations. More than one step may be required. now all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3 CH3CH2C-CN CH3
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