(a) Interpretation: The chair form of α -D-talopyranose is to be drawn. Concept introduction: There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

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Answer 1

Question

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

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Answer 3

Question

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

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Answer 4

Question

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

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Answer 5

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Answer 6

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Answer 7

Chapter 24, Problem 24.36AP

Interpretation Introduction

(a)

Interpretation:

The chair form of α-D-talopyranose is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chair form of propyl β-L-arabinopyranoside is to be drawn.

Concept introduction:

There are two forms of the carbohydrate molecules, pyranose and furanose. The pyranose form of the molecule is a six-membered ring with one oxygen atom in the ring while furanose form is a five-membered ring with one oxygen atom in the ring.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Prob. 24.3P Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Prob. 24.8P Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that there are two forms of the carbohydrate molecules, pyranose and furanos. The hydroxyl group is on the right side of carbon adjacent to the oxygen atom.

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Chapter 24 Solutions