Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 24, Problem 24.19P
Interpretation Introduction

(a)

Interpretation:

A sequence of reactions used in the conversion of Dgalactopyranose to ethyl 2,3,4,6tetraOmethylDgalactopyranoside is to be stated

Concept introduction:

Carbohydrates are a class of organic compounds. They can be present in the form of open chains or ringsThey are usually an aldehyde or ketone with additional hydroxyl groups. They have the general molecular formula, (CH2O)n.

The six-membered ring form of carbohydrates is termed as pyranose. The five-membered ring form of carbohydrates is termed as furanose.

The pyranoses can be classified as α or β based upon the configuration at the anomeric carbon. The anomeric carbon is the one which was a part of the carbonyl group in the straight-chain structure of the carbohydrate.

Interpretation Introduction

(b)

Interpretation:

A sequence of reactions used in the conversion of D-glucopyranose to 2,3,4,6tetraObenzylDglucopyranose is to be stated

Concept introduction:

Carbohydrates are a class of organic compounds. They can be present in the form of open chains or rings.

They are usually an aldehyde or ketone with additional hydroxyl groups. They have the general molecular formula, (CH2O)n.

The 6 membered ring form of carbohydrates is termed as pyranose. This ring contains 5 carbon atoms and 1 an oxygen atom.

The pyranoses can be classified as α or β based upon the configuration at the anomeric carbon. The anomeric carbon is the one which was a part of the carbonyl group in the straight-chain structure of the carbohydrate.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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